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(NH4)2S treatment of the Si (100) surface and its effects on Al/Si Schottky barrier heights

Hu Aibin, Wang Wenwu and Xu Qiuxia

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Abstract: The effect of Si (100) surface S passivation was investigated. A thick film with a high roughness value was formed on the Si surface treated by (NH4)2S solution, which was attributed to physical adsorption of S atoms. SEM and XPS analyses reveal that Si surface atoms were chemically bonded with S atoms after Si surface treatment in NH4OH and (NH4)2S mixing solution. This induces a more ideal value for the Schottky barrier height compared with a diode treated only by HF solution, indicating that surface states originating from dangling bonds are passivated with S atoms.

Key words: Schottky barrier; (NH4)2S treatment; dangling bonds; I–V

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    Received: 18 August 2015 Revised: 24 March 2009 Online: Published: 01 August 2009

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      Hu Aibin, Wang Wenwu, Xu Qiuxia. (NH4)2S treatment of the Si (100) surface and its effects on Al/Si Schottky barrier heights[J]. Journal of Semiconductors, 2009, 30(8): 084001. doi: 10.1088/1674-4926/30/8/084001 Hu A B, Wang W W, Xu Q X. (NH4)2S treatment of the Si (100) surface and its effects on Al/Si Schottky barrier heights[J]. J. Semicond., 2009, 30(8): 084001. doi:  10.1088/1674-4926/30/8/084001.Export: BibTex EndNote
      Citation:
      Hu Aibin, Wang Wenwu, Xu Qiuxia. (NH4)2S treatment of the Si (100) surface and its effects on Al/Si Schottky barrier heights[J]. Journal of Semiconductors, 2009, 30(8): 084001. doi: 10.1088/1674-4926/30/8/084001

      Hu A B, Wang W W, Xu Q X. (NH4)2S treatment of the Si (100) surface and its effects on Al/Si Schottky barrier heights[J]. J. Semicond., 2009, 30(8): 084001. doi:  10.1088/1674-4926/30/8/084001.
      Export: BibTex EndNote

      (NH4)2S treatment of the Si (100) surface and its effects on Al/Si Schottky barrier heights

      doi: 10.1088/1674-4926/30/8/084001
      • Received Date: 2015-08-18
      • Accepted Date: 2009-01-14
      • Revised Date: 2009-03-24
      • Published Date: 2009-07-31

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