SEMICONDUCTOR PHYSICS

Optical transmission in thin films of vanadium compounds

Kh. S. Karimov1, 2, M. Mahroof-Tahir3, M. Saleem1, 4, , N. Ahmad1 and A. Rashid4

+ Author Affiliations

 Corresponding author: M. Saleem, Email:msaleem108@hotmail.com, drsaleem@ymail.com

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Abstract: Thin films of five vanadium compounds/composite:(1) VO2(3-fl) (3-fl=3-Hydroxyflavone), (2) VO(pbd)2 (pbd=1-Phenyl-1, 3-butadione), (3) VO(dbm)2 (dbm=Dibenzoylmethane), (4) VPc (Vanadyl Phthalocyanine) and (5) V2O5-PEPC (V2O5-poly-N-epoxypropylcarbazole composite), were deposited by the drop-casting method from the solution in benzene. The transmittance-irradiance relationships were investigated and the transmission in the visible spectrum and optical images were obtained as well. It was found that the transmittance of the VO2(3-fl), VO(pbd)2, VO(dbm)2 and VPc, was practically independent of the irradiance; whereas the transmittance of V2O5-PEPC decreased by 4% for thin and 9% for thick film with an increase of the irradiance.

Key words: vanadium compound/compositesemiconductorthin filmtransmittanceirradiance



[1]
Parkin I P, Binions R, Piccirillo C, et al. Thermochromic coatings for intelligent architectural glazing. J Nano Research, 2008, 2: 1 http://www.scientific.net/JNanoR.2.1
[2]
Batista C, Teixeira V, Carneiro J. Structural and morphological characterization of magnetron sputtered nanocrystalline vanadium oxide films for thermochromic smart surfaces. J Nano Research, 2008, 2: 21 doi: 10.4028/www.scientific.net/JNanoR.2
[3]
Chain E E. Optical properties of vanadium dioxide and vanadium pentoxide thin films. Appl Opt, 1991, 30: 2782 doi: 10.1364/AO.30.002782
[4]
Maruyama T, Ikuta Y. Vanadium dioxide thin films prepared by chemical vapour deposition from vanadium(Ⅲ) acetylacetonate. J Mater Sci, 1993, 28: 5073 doi: 10.1007/BF00361182
[5]
Sahara M B, Shivashankar S A. Growth of nanowires of β-NaxV2O5 by metalorganic chemical vapor deposition. J Mater Chem, 2003, 13: 2254 doi: 10.1039/B305569H
[6]
Benmoussa M, Ibnouelghazi E, Bennouna A, et al. Structural, electrical and optical properties of sputtered vanadium pentoxide thin films. Thin Solid Films, 1995, 265: 22 doi: 10.1016/0040-6090(95)06617-9
[7]
Qi J, Ning G, Qi X, et al. Structure and optical properties of VO2 film derived from a low temperature sol-gel and facile thermal process. Optoelect Adv Mater Rapid Commun, 2010, 4: 194 doi: 10.1088/0953-8984/20/26/264016/meta
[8]
Batista C, Ribeiro R M, Teixeira V. Synthesis and characterization of VO2-based thermochromic thin films for energy-efficient windows. Nanoscale Res Lett, 2011, 6: 301 doi: 10.1186/1556-276X-6-301
[9]
Mitzi D B, Chondroudis K, Kagan C R. Organic-inorganic electronics. IBM J Res Dev, 2001, 45: 29 doi: 10.1147/rd.451.0029
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Gutman F, Lyons L E. Organic semiconductors. Part A. Robert E. Krieger Publishing Company, Malabar, Florida, 1981 http://www.nature.com/nnano/focus/organics/index.html
[11]
Gutman F, Keyzer H, Lyons L E, et al. Organic semiconductors. Part B. Robert E. Krieger Publishing Company, Malabar, Florida, 1983 https://en.wikipedia.org/wiki/Organic_semiconductor
[12]
Brutting W. Physics of organic semiconductors. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2005 https://www.amazon.com/Physics-Organic-Semiconductors-Wolfgang-tting/dp/3527410538
[13]
Karimov K S. Electric properties of quasi-one dimentional tetracyano-quino-dimethane ion-radical salts crystals under hydro-static pressure. PhD Thesis, Physical Techenical Institute, St. -Petersburg, USSR, 1982 doi: 10.1088/1674-4926/35/7/072002/meta
[14]
Karimov K S, Akhmedov K, Qazi I, et al. Poly-N-epoxypropylcarbazole complexes photocapacitive detectors. J Optoelectron Adv Mater, 2007, 9: 2867 doi: 10.1109%2fSIECPC.2011.5876964
[15]
Akhmedov K M, Karimov K S. Carbazolile polymers. Donish, Dushanbe, 2006 doi: 10.1007/s00289-010-0322-x
[16]
Tahir M M, Karimov K S. Fabrication of heterojunctions and current-voltage characteristics of vanadium coordination compounds. J Optoelectron Adv Mater, 2009, 11: 83 http://www.academia.edu/7781602/Transition_Metal_Oxides_and_Their_Composite_Thin_Films
[17]
Tahir M M, Brezina D, Fatima N, et al. Synthesis and characterization of mononuclear oxovandadium (Ⅳ) complexes and their enzyme inhibition studies with a carbohydrate metabolic enzyme, phosphodiesterase Ⅰ. J Inorg Biochem, 2005, 99: 589 doi: 10.1016/j.jinorgbio.2004.11.015
[18]
Epifanov G I, Moma Y A. Solid state electronics. Visshaia Shkola, Moscow, 1986 http://www.sciencedirect.com/science/journal/00381101
[19]
Yianoulis P, Giannouli M. Thin solid films and nanomaterials for solar energy conversion and energy saving applications. J Nano Research, 2008, 2: 49 doi: 10.4028/www.scientific.net/JNanoR.2
[20]
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[21]
Hadziioannou G, Van Hutten P F. Semi-conducting polymers: chemistry, physics and engineering. WILEY-VCH, Verlag GmbH, Weinheim, 2000 http://www.sciencedirect.com/science/article/pii/S092596350600505X
Fig. 1.  The molecular structures of (1) VO$_{2}$(3-fl), (2) VO(pbd)$_{2}$, (3) VO(dbm)$_{2}$, (4) VPc, and (5) V$_{2}$O$_{5}$-PEPC.

Fig. 2.  The optical images of (1) VO$_{2}$(3-fl), (2) VO(pbd)$_{2}$, (3) VO(dbm)$_{2}$, (4) VPc, and (5) V$_{2}$O$_{5}$-PEPC.

Fig. 3.  Transmittance-input irradiance relationships for (1) VO$_{2}$(3-fl), (2) VO(pbd)$_{2}$, (3) VO(dbm)$_{2}$.

Fig. 4.  Transmittance-input irradiance relationships for (4) VPc, (5) thin film and (6) thick film of V$_{2}$O$_{5}$-PEPC and (7) glass substrate.

[1]
Parkin I P, Binions R, Piccirillo C, et al. Thermochromic coatings for intelligent architectural glazing. J Nano Research, 2008, 2: 1 http://www.scientific.net/JNanoR.2.1
[2]
Batista C, Teixeira V, Carneiro J. Structural and morphological characterization of magnetron sputtered nanocrystalline vanadium oxide films for thermochromic smart surfaces. J Nano Research, 2008, 2: 21 doi: 10.4028/www.scientific.net/JNanoR.2
[3]
Chain E E. Optical properties of vanadium dioxide and vanadium pentoxide thin films. Appl Opt, 1991, 30: 2782 doi: 10.1364/AO.30.002782
[4]
Maruyama T, Ikuta Y. Vanadium dioxide thin films prepared by chemical vapour deposition from vanadium(Ⅲ) acetylacetonate. J Mater Sci, 1993, 28: 5073 doi: 10.1007/BF00361182
[5]
Sahara M B, Shivashankar S A. Growth of nanowires of β-NaxV2O5 by metalorganic chemical vapor deposition. J Mater Chem, 2003, 13: 2254 doi: 10.1039/B305569H
[6]
Benmoussa M, Ibnouelghazi E, Bennouna A, et al. Structural, electrical and optical properties of sputtered vanadium pentoxide thin films. Thin Solid Films, 1995, 265: 22 doi: 10.1016/0040-6090(95)06617-9
[7]
Qi J, Ning G, Qi X, et al. Structure and optical properties of VO2 film derived from a low temperature sol-gel and facile thermal process. Optoelect Adv Mater Rapid Commun, 2010, 4: 194 doi: 10.1088/0953-8984/20/26/264016/meta
[8]
Batista C, Ribeiro R M, Teixeira V. Synthesis and characterization of VO2-based thermochromic thin films for energy-efficient windows. Nanoscale Res Lett, 2011, 6: 301 doi: 10.1186/1556-276X-6-301
[9]
Mitzi D B, Chondroudis K, Kagan C R. Organic-inorganic electronics. IBM J Res Dev, 2001, 45: 29 doi: 10.1147/rd.451.0029
[10]
Gutman F, Lyons L E. Organic semiconductors. Part A. Robert E. Krieger Publishing Company, Malabar, Florida, 1981 http://www.nature.com/nnano/focus/organics/index.html
[11]
Gutman F, Keyzer H, Lyons L E, et al. Organic semiconductors. Part B. Robert E. Krieger Publishing Company, Malabar, Florida, 1983 https://en.wikipedia.org/wiki/Organic_semiconductor
[12]
Brutting W. Physics of organic semiconductors. Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim, 2005 https://www.amazon.com/Physics-Organic-Semiconductors-Wolfgang-tting/dp/3527410538
[13]
Karimov K S. Electric properties of quasi-one dimentional tetracyano-quino-dimethane ion-radical salts crystals under hydro-static pressure. PhD Thesis, Physical Techenical Institute, St. -Petersburg, USSR, 1982 doi: 10.1088/1674-4926/35/7/072002/meta
[14]
Karimov K S, Akhmedov K, Qazi I, et al. Poly-N-epoxypropylcarbazole complexes photocapacitive detectors. J Optoelectron Adv Mater, 2007, 9: 2867 doi: 10.1109%2fSIECPC.2011.5876964
[15]
Akhmedov K M, Karimov K S. Carbazolile polymers. Donish, Dushanbe, 2006 doi: 10.1007/s00289-010-0322-x
[16]
Tahir M M, Karimov K S. Fabrication of heterojunctions and current-voltage characteristics of vanadium coordination compounds. J Optoelectron Adv Mater, 2009, 11: 83 http://www.academia.edu/7781602/Transition_Metal_Oxides_and_Their_Composite_Thin_Films
[17]
Tahir M M, Brezina D, Fatima N, et al. Synthesis and characterization of mononuclear oxovandadium (Ⅳ) complexes and their enzyme inhibition studies with a carbohydrate metabolic enzyme, phosphodiesterase Ⅰ. J Inorg Biochem, 2005, 99: 589 doi: 10.1016/j.jinorgbio.2004.11.015
[18]
Epifanov G I, Moma Y A. Solid state electronics. Visshaia Shkola, Moscow, 1986 http://www.sciencedirect.com/science/journal/00381101
[19]
Yianoulis P, Giannouli M. Thin solid films and nanomaterials for solar energy conversion and energy saving applications. J Nano Research, 2008, 2: 49 doi: 10.4028/www.scientific.net/JNanoR.2
[20]
Brabec C J, Dyakonov V, Parisi J, et al. Organic photovoltaics: concepts and realization. Springer-Verlag, Berlin, Heidelberg, 2003 http://www.springer.com/us/book/9783540004059
[21]
Hadziioannou G, Van Hutten P F. Semi-conducting polymers: chemistry, physics and engineering. WILEY-VCH, Verlag GmbH, Weinheim, 2000 http://www.sciencedirect.com/science/article/pii/S092596350600505X
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    Received: 24 December 2013 Revised: 18 February 2014 Online: Published: 01 July 2014

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      Kh. S. Karimov, M. Mahroof-Tahir, M. Saleem, N. Ahmad, A. Rashid. Optical transmission in thin films of vanadium compounds[J]. Journal of Semiconductors, 2014, 35(7): 072002. doi: 10.1088/1674-4926/35/7/072002 Kh. S. Karimov, M. Mahroof-Tahir, M. Saleem, N. Ahmad, A. Rashid. Optical transmission in thin films of vanadium compounds[J]. J. Semicond., 2014, 35(7): 072002. doi: 10.1088/1674-4926/35/7/072002.Export: BibTex EndNote
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      Kh. S. Karimov, M. Mahroof-Tahir, M. Saleem, N. Ahmad, A. Rashid. Optical transmission in thin films of vanadium compounds[J]. Journal of Semiconductors, 2014, 35(7): 072002. doi: 10.1088/1674-4926/35/7/072002

      Kh. S. Karimov, M. Mahroof-Tahir, M. Saleem, N. Ahmad, A. Rashid. Optical transmission in thin films of vanadium compounds[J]. J. Semicond., 2014, 35(7): 072002. doi: 10.1088/1674-4926/35/7/072002.
      Export: BibTex EndNote

      Optical transmission in thin films of vanadium compounds

      doi: 10.1088/1674-4926/35/7/072002
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      • Corresponding author: M. Saleem, Email:msaleem108@hotmail.com, drsaleem@ymail.com
      • Received Date: 2013-12-24
      • Revised Date: 2014-02-18
      • Published Date: 2014-07-01

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