SEMICONDUCTOR MATERIALS

Impact of GaN transition layers in the growth of GaN epitaxial layer on silicon

Danmei Zhao, Degang Zhao, Desheng Jiang, Zongshun Liu, Jianjun Zhu, Pin Chen, Wei Liu, Xiang Li and Ming Shi

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 Corresponding author: Degang Zhao, Email: dgzhao@semi.ac.cn

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Abstract: A method for growing GaN epitaxial layer on Si (111) substrate is investigated. Due to the large lattice mismatch between GaN and AlN, GaN grown directly above an AlN buffer layer on the Si substrate turns out to be of poor quality. In this study, a GaN transition layer is grown additionally on the AlN buffer before the GaN epitaxial growth. By changing the growth conditions of the GaN transition layer, we can control the growth and merging of islands and control the transfer time from 3D to 2D growth mode. With this method, the crystalline quality of the GaN epitaxial layer can be improved and the crack density is reduced. Here, we have investigated the impact of a transition layer on the crystalline quality and stress evolution of a GaN epitaxial layer with methods of X-ray diffraction, optical microscopy and in situ reflectivity trace. With the increasing thickness of transition layer, the crack decreases and the crystalline quality is improved. But when the transition layer exceeds a critical thickness, the crystalline quality of the epilayer becomes lower and the crack density increases.

Key words: GaNcrackMOCVD



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Fig. 1.  The schematic diagrams of structure (a) for samples A,B,C and D and structure (b) for samples E,F and G.

Fig. 2.  The FWHMs of (0002) XRD of (a) sample B,(b) sample E,(c) sample F and (d) sample G.

Fig. 3.  Optical micrographs of (a) sample B,(b) sample E,(c) sample F and (d) sample G.

Fig. 4.  in situ reflectivity traces of (a) sample B,(b) sample E,(c) sample F and (d) sample G. Sections of I,II and III represent the growth of buffer layer,transition layer and the GaN epitaxial layer respectively.

Table 1.   The growth conditions and FWHMs of (0002) XRD of different samples.

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    Received: 09 December 2014 Revised: Online: Published: 01 June 2015

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      Danmei Zhao, Degang Zhao, Desheng Jiang, Zongshun Liu, Jianjun Zhu, Pin Chen, Wei Liu, Xiang Li, Ming Shi. Impact of GaN transition layers in the growth of GaN epitaxial layer on silicon[J]. Journal of Semiconductors, 2015, 36(6): 063003. doi: 10.1088/1674-4926/36/6/063003 D M Zhao, D G Zhao, D S Jiang, Z S Liu, J J Zhu, P Chen, W Liu, X Li, M Shi. Impact of GaN transition layers in the growth of GaN epitaxial layer on silicon[J]. J. Semicond., 2015, 36(6): 063003. doi: 10.1088/1674-4926/36/6/063003.Export: BibTex EndNote
      Citation:
      Danmei Zhao, Degang Zhao, Desheng Jiang, Zongshun Liu, Jianjun Zhu, Pin Chen, Wei Liu, Xiang Li, Ming Shi. Impact of GaN transition layers in the growth of GaN epitaxial layer on silicon[J]. Journal of Semiconductors, 2015, 36(6): 063003. doi: 10.1088/1674-4926/36/6/063003

      D M Zhao, D G Zhao, D S Jiang, Z S Liu, J J Zhu, P Chen, W Liu, X Li, M Shi. Impact of GaN transition layers in the growth of GaN epitaxial layer on silicon[J]. J. Semicond., 2015, 36(6): 063003. doi: 10.1088/1674-4926/36/6/063003.
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      Impact of GaN transition layers in the growth of GaN epitaxial layer on silicon

      doi: 10.1088/1674-4926/36/6/063003
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      Project supported by the National Natural Science Foundation of China (Nos. 61474110, 61377020, 61376089, 61223005, 61176126), and the National Science Fund for Distinguished Young Scholars (No. 60925017).

      More Information
      • Corresponding author: Email: dgzhao@semi.ac.cn
      • Received Date: 2014-12-09
      • Accepted Date: 2015-01-13
      • Published Date: 2015-01-25

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