SEMICONDUCTOR MATERIALS

Effect of magnesium doping on the light-induced hydrophilicity of ZnO thin films

Huang Kai, Lü Jianguo, Zhang Li, Tang Zhen, Yu Jiangying, Li Ping and Liu Feng

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Abstract: Undoped and Mg-doped ZnO thin films were deposited on Si (111) and quartz substrates by using the sol-gel method. Microstructure, surface topography and water contact angle of the thin films have been measured by X-ray diffraction (XRD), an atomic force microscope (AFM) and water contact angle apparatus, respectively. The XRD results show that all the thin films are polycrystalline with a hexagonal structure and have a preferred orientation along the c-axis perpendicular to the substrate. With the increase of Mg concentration, the RMS roughness increases from 2.14 to 9.56 nm and the contact angle of the un-irradiated thin films decreases from 89° to 82°. The wetting behavior of the resulting films can be reversibly switched from hydrophobic to hydrophilic, through alternation of UV illumination and dark storage. The light-induced efficiency of the thin films increases with the increase of Mg concentration.

Key words: ZnOsol-gelSurface topographyhydrophilicity

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    Received: 20 August 2015 Revised: 17 December 2011 Online: Published: 01 May 2012

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      Huang Kai, Lü Jianguo, Zhang Li, Tang Zhen, Yu Jiangying, Li Ping, Liu Feng. Effect of magnesium doping on the light-induced hydrophilicity of ZnO thin films[J]. Journal of Semiconductors, 2012, 33(5): 053003. doi: 10.1088/1674-4926/33/5/053003 Huang K, Lü J G, Zhang L, Tang Z, Yu J Y, Li P, Liu F. Effect of magnesium doping on the light-induced hydrophilicity of ZnO thin films[J]. J. Semicond., 2012, 33(5): 053003. doi:  10.1088/1674-4926/33/5/053003.Export: BibTex EndNote
      Citation:
      Huang Kai, Lü Jianguo, Zhang Li, Tang Zhen, Yu Jiangying, Li Ping, Liu Feng. Effect of magnesium doping on the light-induced hydrophilicity of ZnO thin films[J]. Journal of Semiconductors, 2012, 33(5): 053003. doi: 10.1088/1674-4926/33/5/053003

      Huang K, Lü J G, Zhang L, Tang Z, Yu J Y, Li P, Liu F. Effect of magnesium doping on the light-induced hydrophilicity of ZnO thin films[J]. J. Semicond., 2012, 33(5): 053003. doi:  10.1088/1674-4926/33/5/053003.
      Export: BibTex EndNote

      Effect of magnesium doping on the light-induced hydrophilicity of ZnO thin films

      doi: 10.1088/1674-4926/33/5/053003
      Funds:

      The National Natural Science Foundation of China (General Program, Key Program, Major Research Plan)

      • Received Date: 2015-08-20
      • Accepted Date: 2011-11-27
      • Revised Date: 2011-12-17
      • Published Date: 2012-04-11

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