SEMICONDUCTOR MATERIALS

The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD

Liang Jing1, 2, Hongling Xiao1, 2, , Xiaoliang Wang1, 2, 3, 4, Cuimei Wang1, 2, Qingwen Deng1, 2, Zhidong Li1, 2, Jieqin Ding1, 2, Zhanguo Wang1, 2 and Xun Hou4

+ Author Affiliations

 Corresponding author: Xiao Hongling, Email:hlxiao@semi.ac.cn

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Abstract: GaN films are grown on cone-shaped patterned sapphire substrates (CPSSs) by metal-organic chemical vapor deposition, and the influence of the temperature during the middle stage of GaN growth on the threading dislocation (TD) density of GaN is investigated. High-resolution X-ray diffraction (XRD) and cathode-luminescence (CL) were used to characterize the GaN films. The XRD results showed that the edge-type dislocation density of GaN grown on CPSS is remarkably reduced compared to that of GaN grown on conventional sapphire substrates (CSSs). Furthermore, when the growth temperature in the middle stage of GaN grown on CPSS decreases, the full width at half maximum of the asymmetry (102) plane of GaN is reduced. This reduction is attributed to the enhancement of vertical growth in the middle stage with a more triangular-like shape and the bending of TDs. The CL intensity spatial mapping results also showed the superior optical properties of GaN grown on CPSS to those of GaN on CSS, and that the density of dark spots of GaN grown on CPSS induced by nonradiative recombination is reduced when the growth temperature in the middle stage decreases.

Key words: GaNthreading dislocationpatterned sapphire substratemetal-organic chemical vapor deposition



[1]
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[2]
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[3]
Zhang Xiaobin, Wang Xiaoliang, Xiao Hongling, et al. InGaN/GaN multiple quantum well solar cells with an enhanced open-circuit voltage. Chin Phys B, 2011, 20(2):028402 doi: 10.1088/1674-1056/20/2/028402
[4]
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[5]
Sugahara T, Hao M, Wang T, et al. Role of dislocation in InGaN phase separation. Jpn J Appl Phys, 1998, 37:L1195 doi: 10.1143/JJAP.37.L1195
[6]
Sakai A, Sunakawa H, Usui A. Defect structure in selectively grown GaN films with low threading dislocation density. Appl Phys Lett, 1997, 71(16):2259 doi: 10.1063/1.120044
[7]
Kato Y, Kitamura S, Hiramatsu K, et al. Selective growth of wurtzite GaN and AlxGa1-xN on GaN/sapphire substrates by metalorganic vapor phase epitaxy. J Cryst Growth, 1994, 144(3/4):133
[8]
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[10]
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[11]
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[12]
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[15]
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[16]
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Fig. 1.  Scanning electron microscope image of the cone-shaped PSS.

Fig. 2.  SEM images of GaN epilayers grown on PSS. (a) Plane view. (b) Cross-sectional view.

Fig. 3.  The high-resolution X-ray diffraction spectra of the GaN layer grown on CPSS and CSS. (a) (002) plane. (b) (102) plane.

Fig. 4.  Schematic map of the growth mode of GaN on CPSS. (a) In the middle stage, and (b) in the final stage (the gray region denotes CPSS, the black region the LT-GaN nucleation layer, and the white trapezoid-shaped region refers to HT-GaN).

Fig. 5.  Plane-view CL mapping images of samples (a) S1, (b) S2 and (c) S3.

Table 1.   The growth conditions for samples S1, S2 and S3.

[1]
Wang X L, Wang C M, Hu G X, et al. Improved DC and RF performance of AlGaN/GaN HEMTs grown by MOCVD on sapphire substrates. Solid-State Electron, 2005, 49(8):1387 doi: 10.1016/j.sse.2005.06.022
[2]
Ponce F, Bour D. Nitride-based semiconductors for blue and green light-emitting devices. Nature, 1997, 386(6623):351 doi: 10.1038/386351a0
[3]
Zhang Xiaobin, Wang Xiaoliang, Xiao Hongling, et al. InGaN/GaN multiple quantum well solar cells with an enhanced open-circuit voltage. Chin Phys B, 2011, 20(2):028402 doi: 10.1088/1674-1056/20/2/028402
[4]
Elsner J, Jones R, Sitch P K, et al. Theory of threading edge and screw dislocations in GaN. Phys Rev Lett, 1997, 79(19):3672 doi: 10.1103/PhysRevLett.79.3672
[5]
Sugahara T, Hao M, Wang T, et al. Role of dislocation in InGaN phase separation. Jpn J Appl Phys, 1998, 37:L1195 doi: 10.1143/JJAP.37.L1195
[6]
Sakai A, Sunakawa H, Usui A. Defect structure in selectively grown GaN films with low threading dislocation density. Appl Phys Lett, 1997, 71(16):2259 doi: 10.1063/1.120044
[7]
Kato Y, Kitamura S, Hiramatsu K, et al. Selective growth of wurtzite GaN and AlxGa1-xN on GaN/sapphire substrates by metalorganic vapor phase epitaxy. J Cryst Growth, 1994, 144(3/4):133
[8]
Kitamura S, Hiramatsu K, Sawaki N. Fabrication of GaN hexagonal pyramids on dot-patterned GaN/sapphire substrates via selective metalorganic vapor phase epitaxy. Jpn J Appl Phys, 1995, 34:L1184 doi: 10.1143/JJAP.34.L1184
[9]
Feng Z H, Qi Y D, Lu Z D, et al. GaN-based blue light-emitting diodes grown and fabricated on patterned sapphire substrates by metalorganic vapor-phase epitaxy. J Cryst Growth, 2004, 272(1-4):327 doi: 10.1016/j.jcrysgro.2004.08.070
[10]
Tadatomo K, Okagawa H, Ohuchi Y, et al. High output power InGaN ultraviolet light-emitting diodes fabricated on patterned substrates using metalorganic vapor phase epitaxy. Jpn J Appl Phys, 2001, 40:L583 doi: 10.1143/JJAP.40.L583
[11]
Gao H, Yan F, Zhang Y, et al. Enhancement of the light output power of InGaN/GaN light-emitting diodes grown on pyramidal patterned sapphire substrates in the micro-and nanoscale. J Appl Phys, 2008, 103(1):014314 doi: 10.1063/1.2830981
[12]
Rorma P T, Ali M, Svensk O, et al. An investigation of structural properties of GaN films grown on patterned sapphire substrates by MOVPE. Physica B:Condensed Matter, 2009, 404(23/24):4911 doi: 10.1134%2FS1063785015030189.pdf
[13]
Kissinger S, Jeong S M, Yun S H, et al. Enhancement in emission angle of the blue LED chip fabricated on lens patterned sapphire. Solid-State Electron, 2010, 54(5):509 doi: 10.1016/j.sse.2009.11.005
[14]
Lee K S, Kwack H S, Hwang J S, et al. Spatial correlation between optical properties and defect formation in GaN thin films laterally overgrown on cone-shaped patterned sapphire substrates. J Appl Phys, 2010, 107(10):103506 doi: 10.1063/1.3388014
[15]
Lee J H, Lee D Y, Oh B W, et al. Comparison of InGaN-based LEDs grown on conventional sapphire and cone-shape-patterned sapphire substrate. IEEE Trans Electron Devices, 2010, 57(1):157 doi: 10.1109/TED.2009.2034495
[16]
Wang H W, Chen H C, Chang Y A, et al. Conversion efficiency enhancement of GaN/In0.11Ga0.89N solar cells with nano patterned sapphire and biomimetic surface antireflection process. IEEE Photonics Technol Lett, 2011, 23(18):1304 doi: 10.1109/LPT.2011.2160051
[17]
Srikant V, Speck J S, Clarke D R. Mosaic structure in epitaxial thin films having large lattice mismatch. J Appl Phys, 1997, 82(9):4286 doi: 10.1063/1.366235
[18]
Hiramatsu K, Nishiyama K, Onishi M, et al. Fabrication and characterization of low defect density GaN using facet-controlled epitaxial lateral overgrowth (FACELO). J Cryst Growth, 2000, 221(1-4):316 doi: 10.1016/S0022-0248(00)00707-7
[19]
Kapolnek D, Underwood R D, Keller B P, et al. Selective area epitaxy of GaN for electron field emission devices. J Cryst Growth, 1997, 170(1-4):340 doi: 10.1016/S0022-0248(96)00620-3
[20]
Kazumasa H. Epitaxial lateral overgrowth techniques used in group Ⅲ nitride epitaxy. J Phys:Condensed Matter, 2001, 13(32):6961 doi: 10.1088/0953-8984/13/32/306
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    Received: 24 April 2013 Revised: 02 May 2013 Online: Published: 01 November 2013

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      Liang Jing, Hongling Xiao, Xiaoliang Wang, Cuimei Wang, Qingwen Deng, Zhidong Li, Jieqin Ding, Zhanguo Wang, Xun Hou. The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD[J]. Journal of Semiconductors, 2013, 34(11): 113002. doi: 10.1088/1674-4926/34/11/113002 L Jing, H L Xiao, X L Wang, C M Wang, Q W Deng, Z D Li, J Q Ding, Z G Wang, X Hou. The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD[J]. J. Semicond., 2013, 34(11): 113002. doi: 10.1088/1674-4926/34/11/113002.Export: BibTex EndNote
      Citation:
      Liang Jing, Hongling Xiao, Xiaoliang Wang, Cuimei Wang, Qingwen Deng, Zhidong Li, Jieqin Ding, Zhanguo Wang, Xun Hou. The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD[J]. Journal of Semiconductors, 2013, 34(11): 113002. doi: 10.1088/1674-4926/34/11/113002

      L Jing, H L Xiao, X L Wang, C M Wang, Q W Deng, Z D Li, J Q Ding, Z G Wang, X Hou. The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD[J]. J. Semicond., 2013, 34(11): 113002. doi: 10.1088/1674-4926/34/11/113002.
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      The growth and characterization of GaN films on cone-shaped patterned sapphire by MOCVD

      doi: 10.1088/1674-4926/34/11/113002
      Funds:

      the State Key Development Program for Basic Research of China 2012CB619303

      Project supported by the National Natural Science Foundation of China (Nos. 61076052, 60906006), the State Key Development Program for Basic Research of China (No. 2012CB619303), and the National High Technology Research and Development Program of China (No. 2011AA050514)

      the National High Technology Research and Development Program of China 2011AA050514

      the National Natural Science Foundation of China 60906006

      the National Natural Science Foundation of China 61076052

      More Information
      • Corresponding author: Xiao Hongling, Email:hlxiao@semi.ac.cn
      • Received Date: 2013-04-24
      • Revised Date: 2013-05-02
      • Published Date: 2013-11-01

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