SEMICONDUCTOR TECHNOLOGY

Evaluation of planarization performance for a novel alkaline copper slurry under a low abrasive concentration

Mengting Jiang, Yuling Liu, Haobo Yuan, Guodong Chen and Weijuan Liu

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 Corresponding author: Jiang Mengting, Email:jmtlyh@163.com

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Abstract: A novel alkaline copper slurry that possesses a relatively high planarization performance is investigated under a low abrasive concentration. Based on the action mechanism of CMP, the feasibility of using one type of slurry in copper bulk elimination process and residual copper elimination process, with different process parameters, was analyzed. In addition, we investigated the regular change of abrasive concentration effect on copper and tantalum removal rate and within wafer non-uniformity (WIWNU) in CMP process. When the abrasive concentration is 3 wt%, in bulk elimination process, the copper removal rate achieves 6125 Å/min, while WIWNU is 3.5%, simultaneously. In residual copper elimination process, the copper removal rate is approximately 2700 Å/min, while WIWNU is 2.8%. Nevertheless, the tantalum removal rate is 0 Å/min, which indicates that barrier layer isn't eliminated in residual copper elimination process. The planarization experimental results show that an excellent planarization performance is obtained with a relatively high copper removal rate in bulk elimination process. Meanwhile, after residual copper elimination process, the dishing value increased inconspicuously, in a controllable range, and the wafer surface roughness is only 0.326 nm (sq < 1 nm) after polishing. By comparison, the planarization performance and surface quality of alkaline slurry show almost no major differences with two kinds of commercial acid slurries after polishing. All experimental results are conducive to research and improvement of alkaline slurry in the future.

Key words: alkaline slurryabrasive concentrationplanarization performanceacid slurry



[1]
Pandija S, Roy D, Babu S V. Achievement of high planarization efficiency in CMP of copper at a reduced down pressure. Microelectron Eng, 2009, 86(3):367 doi: 10.1016/j.mee.2008.11.047
[2]
Zantye P B, Kumar A, Sikdar A K. Chemical mechanical planarization for microelectronics application. Mater Sci Eng, 2004, 45:89 doi: 10.1016/j.mser.2004.06.002
[3]
Fayolle M, Romagna F. Copper CMP evaluation:planarization issues. Microelectron Eng 1997, 37/38:135 doi: 10.1016/S0167-9317(97)00104-4
[4]
Wang C W, Gao J J, Tian J Y, et al. Chemical mechanical planarization of barrier layers by using a weakly alkaline slurry. Microelectron Eng, 2013, 108:71 doi: 10.1016/j.mee.2013.04.001
[5]
Wang C W, Liu Y L, Niu X H, et al. An advanced alkaline slurry for barrier chemical mechanical planarization on patterned wafers. Journal of Semiconductors, 2012, 33(4):046001 doi: 10.1088/1674-4926/33/4/046001
[6]
Murata J, Sadakuni S, Okamoto T, et al. Structural and chemical characteristics of atomically smooth GaN surfaces prepared by abrasive-free polishing with Pt catalyst. J Cryst Growth, 2012, 349:83 doi: 10.1016/j.jcrysgro.2012.04.007
[7]
Li Y, Liu Y L, Niu X H, et al. Application of a macromolecular chelating agent in chemical mechanical polishing of copper film under the condition of low pressure and low abrasive concentration. Journal of Semiconductors, 2014, 35(1):016001 doi: 10.1088/1674-4926/35/1/016001
[8]
Zhang W, Lu X C, Liu Y H, et al. Inhibitors for organic phosphonic acid system abrasive free polishing of Cu. Appl Surf Sci, 2009, 255:4114 doi: 10.1016/j.apsusc.2008.10.096
[9]
Pandija S, Roy D, Babu S V. Chemical mechanical planarization of copper using abrasive-free solutions of oxalic acid and hydrogen peroxide. Mater Chem Phys, 2007, 102(2/3):144
[10]
Zhang W, Lu X C, Liu Y H, et al. Effect of pH on material removal rate of Cu in abrasive-free polishing. J Electrochem Soc, 2009, 156(3):176
[11]
Lee H, Park B, Jeong H. Mechanical effect of process condition and abrasive concentration on material removal rate profile in copper chemical mechanical planarization. J Mater Processing Technol, 2009, 209(4):1729 doi: 10.1016/j.jmatprotec.2008.04.021
[12]
Nguyen V, Vankranenburg H, Woerlee P. Dependency of dishing on polish time and slurry chemistry in Cu CMP. Microelectron Eng, 2000, 50:403 doi: 10.1016/S0167-9317(99)00308-1
[13]
Yin K D, Wang S L, Liu Y L, et al. Evaluation of planarization capability of copper slurry in the CMP process. Journal of Semiconductors, 2013, 34(3):036002 doi: 10.1088/1674-4926/34/3/036002
Fig. 1.  (Color online) The schematic illustration of copper CMP process

Fig. 2.  Cross sectional view of the 300 mm copper wafer. (a) Copper blanket wafer. (b) Copper pattern wafer

Fig. 3.  Copper removal rate and WIWNU as a function of abrasive concentration (a) In bulk copper elimination process. (b) In residual copper elimination process

Fig. 4.  Tantalum removal rate as a function of abrasive concentration in residual copper elimination process

Fig. 5.  Step height reduction as a function of polishing time. (a) The alkaline slurry. (b) The commercial acid slurry

Fig. 6.  Schematic illustration of chemical reaction model in CMP process

Fig. 7.  The AFM images of the copper wafer surface. (a) Before polishing and (b) After polishing using the alkaline slurry

Fig. 8.  The AFM images of the copper wafer surface. (a) Before polishing and (b) After polishing using the commercial acid slurries

Table 1.   Process parameters in experiments

[1]
Pandija S, Roy D, Babu S V. Achievement of high planarization efficiency in CMP of copper at a reduced down pressure. Microelectron Eng, 2009, 86(3):367 doi: 10.1016/j.mee.2008.11.047
[2]
Zantye P B, Kumar A, Sikdar A K. Chemical mechanical planarization for microelectronics application. Mater Sci Eng, 2004, 45:89 doi: 10.1016/j.mser.2004.06.002
[3]
Fayolle M, Romagna F. Copper CMP evaluation:planarization issues. Microelectron Eng 1997, 37/38:135 doi: 10.1016/S0167-9317(97)00104-4
[4]
Wang C W, Gao J J, Tian J Y, et al. Chemical mechanical planarization of barrier layers by using a weakly alkaline slurry. Microelectron Eng, 2013, 108:71 doi: 10.1016/j.mee.2013.04.001
[5]
Wang C W, Liu Y L, Niu X H, et al. An advanced alkaline slurry for barrier chemical mechanical planarization on patterned wafers. Journal of Semiconductors, 2012, 33(4):046001 doi: 10.1088/1674-4926/33/4/046001
[6]
Murata J, Sadakuni S, Okamoto T, et al. Structural and chemical characteristics of atomically smooth GaN surfaces prepared by abrasive-free polishing with Pt catalyst. J Cryst Growth, 2012, 349:83 doi: 10.1016/j.jcrysgro.2012.04.007
[7]
Li Y, Liu Y L, Niu X H, et al. Application of a macromolecular chelating agent in chemical mechanical polishing of copper film under the condition of low pressure and low abrasive concentration. Journal of Semiconductors, 2014, 35(1):016001 doi: 10.1088/1674-4926/35/1/016001
[8]
Zhang W, Lu X C, Liu Y H, et al. Inhibitors for organic phosphonic acid system abrasive free polishing of Cu. Appl Surf Sci, 2009, 255:4114 doi: 10.1016/j.apsusc.2008.10.096
[9]
Pandija S, Roy D, Babu S V. Chemical mechanical planarization of copper using abrasive-free solutions of oxalic acid and hydrogen peroxide. Mater Chem Phys, 2007, 102(2/3):144
[10]
Zhang W, Lu X C, Liu Y H, et al. Effect of pH on material removal rate of Cu in abrasive-free polishing. J Electrochem Soc, 2009, 156(3):176
[11]
Lee H, Park B, Jeong H. Mechanical effect of process condition and abrasive concentration on material removal rate profile in copper chemical mechanical planarization. J Mater Processing Technol, 2009, 209(4):1729 doi: 10.1016/j.jmatprotec.2008.04.021
[12]
Nguyen V, Vankranenburg H, Woerlee P. Dependency of dishing on polish time and slurry chemistry in Cu CMP. Microelectron Eng, 2000, 50:403 doi: 10.1016/S0167-9317(99)00308-1
[13]
Yin K D, Wang S L, Liu Y L, et al. Evaluation of planarization capability of copper slurry in the CMP process. Journal of Semiconductors, 2013, 34(3):036002 doi: 10.1088/1674-4926/34/3/036002
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    Received: 01 April 2014 Revised: 23 May 2014 Online: Published: 01 November 2014

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      Mengting Jiang, Yuling Liu, Haobo Yuan, Guodong Chen, Weijuan Liu. Evaluation of planarization performance for a novel alkaline copper slurry under a low abrasive concentration[J]. Journal of Semiconductors, 2014, 35(11): 116002. doi: 10.1088/1674-4926/35/11/116002 M T Jiang, Y L Liu, H B Yuan, G D Chen, W J Liu. Evaluation of planarization performance for a novel alkaline copper slurry under a low abrasive concentration[J]. J. Semicond., 2014, 35(11): 116002. doi: 10.1088/1674-4926/35/11/116002.Export: BibTex EndNote
      Citation:
      Mengting Jiang, Yuling Liu, Haobo Yuan, Guodong Chen, Weijuan Liu. Evaluation of planarization performance for a novel alkaline copper slurry under a low abrasive concentration[J]. Journal of Semiconductors, 2014, 35(11): 116002. doi: 10.1088/1674-4926/35/11/116002

      M T Jiang, Y L Liu, H B Yuan, G D Chen, W J Liu. Evaluation of planarization performance for a novel alkaline copper slurry under a low abrasive concentration[J]. J. Semicond., 2014, 35(11): 116002. doi: 10.1088/1674-4926/35/11/116002.
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      Evaluation of planarization performance for a novel alkaline copper slurry under a low abrasive concentration

      doi: 10.1088/1674-4926/35/11/116002
      Funds:

      the 02 Major Program of the National Medium-Long Term Science and Technology Development Project of China 2009ZX02308

      Project supported by the 02 Major Program of the National Medium-Long Term Science and Technology Development Project of China (No. 2009ZX02308)

      More Information
      • Corresponding author: Jiang Mengting, Email:jmtlyh@163.com
      • Received Date: 2014-04-01
      • Revised Date: 2014-05-23
      • Published Date: 2014-11-01

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