SEMICONDUCTOR DEVICES

Direct-bonded four-junction GaAs solar cells

Jingman Shen, Lijie Sun, Kaijian Chen, Wei Zhang and Xunchun Wang

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 Corresponding author: Lijie Sun, Email: sunlijielu@163.com

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Abstract: Direct wafer bonding technology is able to integrate two smooth wafers and thus can be used in fabricating III-V multijunction solar cells with lattice mismatch. In order to monolithically interconnect between the GaInP/GaAs and InGaAsP/InGaAs subcells, the bonded GaAs/InP heterojunction must be a highly conductive ohmic junction or a tunnel junction. Three types of bonding interfaces were designed by tuning the conduction type and doping elements of GaAs and InP. The electrical properties of p-GaAs (Zn doped)/n-InP (Si doped), p-GaAs (C doped)/n-InP (Si doped) and n-GaAs (Si doped)/n-InP (Si doped) bonded heterojunctions were analyzed from the I-V characteristics. The wafer bonding process was investigated by improving the quality of the sample surface and optimizing the bonding parameters such as bonding temperature, bonding pressure, bonding time and so on. Finally, GaInP/GaAs/InGaAsP/InGaAs 4-junction solar cells have been prepared by a direct wafer bonding technique with the high efficiency of 34.14% at the AM0 condition (1 Sun).

Key words: solar cellgallium arsenidewafer bonding



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Fig. 1.  The typical structure of the III-V multijunctions solar cell via direct wafer bonding process.

Fig. 2.  The AFM image of (a) GaAs and (b) InP surfaces.

Fig. 3.  SAM of DWB 4J solar cell (a) without and (b) with the megasonic cleaning.

Fig. 4.  Structures of various bonded GaAs/InP heterointerfaces.

Fig. 5.  $I$-$V$ characteristics of various bonded GaAs/InP heterointerfaces.

Fig. 6.  Photovoltaic $I$-$V$ curves of DWB 4J solar cells with different types of bonding interfaces. (a) Type A. (b) Type B. (c) Type C.

Table 1.   Summarization of the properties of 4J solar cells with different types of bonding interfaces.

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    Received: 21 October 2014 Revised: Online: Published: 01 June 2015

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      Jingman Shen, Lijie Sun, Kaijian Chen, Wei Zhang, Xunchun Wang. Direct-bonded four-junction GaAs solar cells[J]. Journal of Semiconductors, 2015, 36(6): 064012. doi: 10.1088/1674-4926/36/6/064012 J M Shen, L J Sun, K J Chen, W Zhang, X C Wang. Direct-bonded four-junction GaAs solar cells[J]. J. Semicond., 2015, 36(6): 064012. doi: 10.1088/1674-4926/36/6/064012.Export: BibTex EndNote
      Citation:
      Jingman Shen, Lijie Sun, Kaijian Chen, Wei Zhang, Xunchun Wang. Direct-bonded four-junction GaAs solar cells[J]. Journal of Semiconductors, 2015, 36(6): 064012. doi: 10.1088/1674-4926/36/6/064012

      J M Shen, L J Sun, K J Chen, W Zhang, X C Wang. Direct-bonded four-junction GaAs solar cells[J]. J. Semicond., 2015, 36(6): 064012. doi: 10.1088/1674-4926/36/6/064012.
      Export: BibTex EndNote

      Direct-bonded four-junction GaAs solar cells

      doi: 10.1088/1674-4926/36/6/064012
      Funds:

      Project supported by the Shanghai Rising-Star Program (No. 14QB1402800).

      More Information
      • Corresponding author: Email: sunlijielu@163.com
      • Received Date: 2014-10-21
      • Accepted Date: 2014-12-08
      • Published Date: 2015-01-25

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