SEMICONDUCTOR TECHNOLOGY

Evaluation of planarization capability of copper slurry in the CMP process

Kangda Yin, Shengli Wang, Yuling Liu, Chenwei Wang and Xiang Li

+ Author Affiliations

 Corresponding author: Yin Kangda, yinkangda@126.com; Wang Shengli, wsl619@126.com

PDF

Abstract: The evaluation methods of planarization capability of copper slurry are investigated. Planarization capability and material removal rate are the most essential properties of slurry. The goal of chemical mechanical polishing (CMP) is to achieve a flat and smooth surface. Planarization capability is the elimination capability of the step height on the copper pattern wafer surface, and reflects the passivation capability of the slurry to a certain extent. Through analyzing the planarization mechanism of the CMP process and experimental results, the planarization capability of the slurry can be evaluated by the following five aspects:pressure sensitivity, temperature sensitivity, static etch rate, planarization efficiency and saturation properties.

Key words: planarization capabilitychemical mechanical polishingpressure sensitivitytemperature sensitivitysaturation properties



[1]
Fayolle M, Romagna F. Copper CMP evaluation:planarization issues. Microelectron Eng, 1997, 37/38:135 doi: 10.1016/S0167-9317(97)00104-4
[2]
Pandija S, Roy D, Babu S V. Chemical mechanical planarization of copper using abrasive-free solutions of oxalic acid and hydrogen peroxide. Mater Chem Phys, 2007, 102:141 http://cat.inist.fr/?aModele=afficheN&cpsidt=18617785
[3]
Price D T, Gutmann R J, Murarka S P. Damascene copper interconnects with polymer ILDs. Thin Solid Films, 1997, 308/309:523 doi: 10.1016/S0040-6090(97)00479-3
[4]
Kriz J, Angelkort C, Czekalla M, et al. Overview of dual damascene integration schemes in Cu BEOL integration. Microelectron Eng, 2008, 85:2128 doi: 10.1016/j.mee.2008.05.034
[5]
Ruan W B, Chen L, Li Z G, et al. Effects of pattern characteristics on copper CMP. Journal of Semiconductors, 2009, 30:046001 doi: 10.1088/1674-4926/30/4/046001
[6]
Nguyen V H, Daamen R, Hoofman R. Impact of different slurry and polishing pad choices on the planarization efficiency of a copper CMP process. Microelectron Eng, 2004, 76:95 doi: 10.1016/j.mee.2004.07.019
[7]
Su J X, Du J X, Ma L J, et al. Material removal rate of 6H-SiC crystal substrate CMP using an alumina (Al2O3) abrasive. Journal of Semiconductors, 2012, 33:106003 doi: 10.1088/1674-4926/33/10/106003
[8]
Zeidler D, Plötner M, Drescher K. Endpoint detection method for CMP of copper. Microelectron Eng, 2000, 50:411 doi: 10.1016/S0167-9317(99)00309-3
[9]
Nguyen V, VanKranenburg H, Woerlee P. Dependency of dishing on polish time and slurry chemistry in Cu CMP. Microelectron Eng, 2000, 50:403 doi: 10.1016/S0167-9317(99)00308-1
[10]
Noh K, Saka N, Chun J H. Effect of slurry selectivity on dielectric erosion and copper dishing in copper chemical-mechanical polishing. Cirp Ann-Manuf Tech, 2004, 53:463 doi: 10.1016/S0007-8506(07)60740-9
[11]
Lee H, Park B, Jeong H. Mechanical effect of process condition and abrasive concentration on material removal rate profile in copper chemical mechanical planarization. J Mater Process Technol, 2009, 209:1729 doi: 10.1016/j.jmatprotec.2008.04.021
[12]
Pandija S, Roy D, Babu S V. Achievement of high planarization efficiency in CMP of copper at a reduced down pressure. Microelectron Eng, 2009, 86:367 doi: 10.1016/j.mee.2008.11.047
[13]
Wang C W, Liu Y L, Niu X H, et al. An advanced alkaline slurry for barrier chemical mechanical planarization on patterned wafers. Journal of Semiconductors, 2012, 33:046001 doi: 10.1088/1674-4926/33/4/046001
Fig. 1.  Test position of the step height and dishing on the 300 mm copper pattern wafer.

Fig. 2.  Copper removal rate versus down pressure and temperature. (a) Pressure sensitivity. (b) Temperature sensitivity.

Fig. 3.  Comparison of static etch rate between three kinds of slurry.

Fig. 4.  Step height on the 300 mm copper pattern wafer pre-CMP.

Fig. 5.  Step height reduction versus removed layer thickness.

Fig. 6.  Dishing post over-polish for 60 s with slurry 3.

Fig. 7.  Dishing versus over-polish time.

[1]
Fayolle M, Romagna F. Copper CMP evaluation:planarization issues. Microelectron Eng, 1997, 37/38:135 doi: 10.1016/S0167-9317(97)00104-4
[2]
Pandija S, Roy D, Babu S V. Chemical mechanical planarization of copper using abrasive-free solutions of oxalic acid and hydrogen peroxide. Mater Chem Phys, 2007, 102:141 http://cat.inist.fr/?aModele=afficheN&cpsidt=18617785
[3]
Price D T, Gutmann R J, Murarka S P. Damascene copper interconnects with polymer ILDs. Thin Solid Films, 1997, 308/309:523 doi: 10.1016/S0040-6090(97)00479-3
[4]
Kriz J, Angelkort C, Czekalla M, et al. Overview of dual damascene integration schemes in Cu BEOL integration. Microelectron Eng, 2008, 85:2128 doi: 10.1016/j.mee.2008.05.034
[5]
Ruan W B, Chen L, Li Z G, et al. Effects of pattern characteristics on copper CMP. Journal of Semiconductors, 2009, 30:046001 doi: 10.1088/1674-4926/30/4/046001
[6]
Nguyen V H, Daamen R, Hoofman R. Impact of different slurry and polishing pad choices on the planarization efficiency of a copper CMP process. Microelectron Eng, 2004, 76:95 doi: 10.1016/j.mee.2004.07.019
[7]
Su J X, Du J X, Ma L J, et al. Material removal rate of 6H-SiC crystal substrate CMP using an alumina (Al2O3) abrasive. Journal of Semiconductors, 2012, 33:106003 doi: 10.1088/1674-4926/33/10/106003
[8]
Zeidler D, Plötner M, Drescher K. Endpoint detection method for CMP of copper. Microelectron Eng, 2000, 50:411 doi: 10.1016/S0167-9317(99)00309-3
[9]
Nguyen V, VanKranenburg H, Woerlee P. Dependency of dishing on polish time and slurry chemistry in Cu CMP. Microelectron Eng, 2000, 50:403 doi: 10.1016/S0167-9317(99)00308-1
[10]
Noh K, Saka N, Chun J H. Effect of slurry selectivity on dielectric erosion and copper dishing in copper chemical-mechanical polishing. Cirp Ann-Manuf Tech, 2004, 53:463 doi: 10.1016/S0007-8506(07)60740-9
[11]
Lee H, Park B, Jeong H. Mechanical effect of process condition and abrasive concentration on material removal rate profile in copper chemical mechanical planarization. J Mater Process Technol, 2009, 209:1729 doi: 10.1016/j.jmatprotec.2008.04.021
[12]
Pandija S, Roy D, Babu S V. Achievement of high planarization efficiency in CMP of copper at a reduced down pressure. Microelectron Eng, 2009, 86:367 doi: 10.1016/j.mee.2008.11.047
[13]
Wang C W, Liu Y L, Niu X H, et al. An advanced alkaline slurry for barrier chemical mechanical planarization on patterned wafers. Journal of Semiconductors, 2012, 33:046001 doi: 10.1088/1674-4926/33/4/046001
  • Search

    Advanced Search >>

    GET CITATION

    shu

    Export: BibTex EndNote

    Article Metrics

    Article views: 2439 Times PDF downloads: 23 Times Cited by: 0 Times

    History

    Received: 19 August 2012 Revised: 16 September 2012 Online: Published: 01 March 2013

    Catalog

      Email This Article

      User name:
      Email:*请输入正确邮箱
      Code:*验证码错误
      Kangda Yin, Shengli Wang, Yuling Liu, Chenwei Wang, Xiang Li. Evaluation of planarization capability of copper slurry in the CMP process[J]. Journal of Semiconductors, 2013, 34(3): 036002. doi: 10.1088/1674-4926/34/3/036002 K D Yin, S L Wang, Y L Liu, C W Wang, X Li. Evaluation of planarization capability of copper slurry in the CMP process[J]. J. Semicond., 2013, 34(3): 036002. doi: 10.1088/1674-4926/34/3/036002.Export: BibTex EndNote
      Citation:
      Kangda Yin, Shengli Wang, Yuling Liu, Chenwei Wang, Xiang Li. Evaluation of planarization capability of copper slurry in the CMP process[J]. Journal of Semiconductors, 2013, 34(3): 036002. doi: 10.1088/1674-4926/34/3/036002

      K D Yin, S L Wang, Y L Liu, C W Wang, X Li. Evaluation of planarization capability of copper slurry in the CMP process[J]. J. Semicond., 2013, 34(3): 036002. doi: 10.1088/1674-4926/34/3/036002.
      Export: BibTex EndNote

      Evaluation of planarization capability of copper slurry in the CMP process

      doi: 10.1088/1674-4926/34/3/036002
      Funds:

      the Special Project Items No. 2 in National Long-term Technology Development Plan, China 2009ZX02308

      Project supported by the Special Project Items No. 2 in National Long-term Technology Development Plan, China (No. 2009ZX02308)

      More Information
      • Corresponding author: Yin Kangda, yinkangda@126.com; Wang Shengli, wsl619@126.com
      • Received Date: 2012-08-19
      • Revised Date: 2012-09-16
      • Published Date: 2013-03-01

      Catalog

        /

        DownLoad:  Full-Size Img  PowerPoint
        Return
        Return