SEMICONDUCTOR DEVICES

A p-silicon nanowire/n-ZnO thin film heterojunction diode prepared by thermal evaporation

Purnima Hazra and S. Jit

+ Author Affiliations

 Corresponding author: Purnima Hazra, Email: phazra.rs.ece@itbhu.ac.in

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Abstract: This paper represents the electrical and optical characteristics of a SiNW/ZnO heterojunction diode and subsequent studies on the photodetection properties of the diode in the ultraviolet (UV) wavelength region. In this work, silicon nanowire arrays were prepared on p-type (100)-oriented Si substrate by an electroless metal deposition and etching method with the help of ultrasonication. After that, catalyst-free deposition of zinc oxide (ZnO) nanowires on a silicon nanowire (SiNW) array substrate was done by utilizing a simple and cost-effective thermal evaporation technique without using a buffer layer. The SEM and XRD techniques are used to show the quality of the as-grown ZnO nanowire film. The junction properties of the diode are evaluated by measuring current-voltage and capacitance-voltage characteristics. The diode has a well-defined rectifying behavior with a rectification ratio of 190 at ±2 V, turn-on voltage of 0.5 V, and barrier height is 0.727 eV at room temperature under dark conditions. The photodetection parameters of the diode are investigated in the bias voltage range of ±2 V. The diode shows responsivity of 0.8 A/W at a bias voltage of 2 V under UV illumination (wavelength=365 nm). The characteristics of the device indicate that it can be used for UV detection applications in nano-optoelectronic and photonic devices.

Key words: silicon nanowireZnO nanowireheterojunction diodeinterfacebarrier heightphoto responsivity



[1]
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[2]
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[3]
Chirakkara S, Krupanidhi S B. Study of n-ZnO/p-Si (100) thin film heterojunctions by pulsed laser deposition without buffer layer. Thin Solid Films, 2012, 520(18):5894 doi: 10.1016/j.tsf.2012.05.003
[4]
Vaezi M R, Sadrnezhaad S K. Effects of substrate material and annealing temperature on morphology of zinc oxide films. Mater Sci Technol, 2006, 22(3):308 doi: 10.1179/174328406X78361
[5]
Ding J N, Liu Y B, Tan C B, et al. Investigations into the impact of various substrates and ZnO ultra thin seed layers prepared by atomic layer deposition on growth of ZnO nanowire array. Nanoscale Res Lett, 2012, 7(1):368 doi: 10.1186/1556-276X-7-368
[6]
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[7]
Polsongkram D, Chamninok P, Pukird S, et al. Effect of synthesis conditions on the growth of ZnO nanorods via hydrothermal method. Physica B, 2008, 403(19/20):3713
[8]
Um H D, Moiz S A, Park K T, et al. Highly selective spectral response with enhanced responsivity of n-ZnO/p-Si radial heterojunction nanowire photodiode. Appl Phys Lett, 2011, 98(3):033102 doi: 10.1063/1.3543845
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Sun K, Jing Y, Park N, et al. Solution synthesis of large-scale, high-sensitivity ZnO/Si hierarchical nanoheterostructure photodetectors. J Am Chem Soc, 2010, 132(44):15465 doi: 10.1021/ja1038424
[13]
Choi J H, Das S N, Moon K J, et al. Fabrication and characterization of p-Si nanowires/ZnO film heterojunction diode. Solid-State Electron, 2010, 54(12):1582 doi: 10.1016/j.sse.2010.07.015
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Zhou H, Fang G, Yuan L, et al. Deep ultraviolet and near infrared photodiode based on n-ZnO/p-silicon nanowire heterojunction fabricated at low temperature. Appl Phys Lett, 2009, 94(1):013503 doi: 10.1063/1.3064161
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Hu J, Chen Z, Sun Y, et al. ZnO-Si side-to-side biaxial nanowire heterostructures with improved luminescence. J Mater Chem, 2009, 19(38):7011 doi: 10.1039/b902201e
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Seo O, Kim H, Jo J. Anomalous capacitance change in low-temperature grown ZnO thin-film transistors. Eur Phys J Appl Phys, 2010, 52(1):10501 doi: 10.1051/epjap/2010129
Fig. 1.  (a) SEM image and (b) XRD spectra of the as-prepared ZnO nanowire thin film on a SiNW array substrate.

Fig. 2.  Current–voltage characteristics of the SiNW/ZnO heterojunction diode at room temperature under dark conditions.

Fig. 3.  Capacitance–voltage characteristics of a SiNW/ZnO heterojunction diode at room temperature.

Fig. 4.  Current–voltage characteristics of a SiNW/ZnO heterojunction diode under dark and illuminated conditions; (inset) schematic diagram of the Ag/SiNW/ZNO/Al device structure.

[1]
Ali G M, Singh S, Chakrabarti P. Ultraviolet ZnO photodetectors with high gain. J Electron Sci Technol, 2010, 8(1):55
[2]
Periasamy C, Chakrabarti P. Electrical and optical characterization of ZnO based nano and large area Schottky contacts. Curr Appl Phys, 2011, 11(4):959 doi: 10.1016/j.cap.2010.10.007
[3]
Chirakkara S, Krupanidhi S B. Study of n-ZnO/p-Si (100) thin film heterojunctions by pulsed laser deposition without buffer layer. Thin Solid Films, 2012, 520(18):5894 doi: 10.1016/j.tsf.2012.05.003
[4]
Vaezi M R, Sadrnezhaad S K. Effects of substrate material and annealing temperature on morphology of zinc oxide films. Mater Sci Technol, 2006, 22(3):308 doi: 10.1179/174328406X78361
[5]
Ding J N, Liu Y B, Tan C B, et al. Investigations into the impact of various substrates and ZnO ultra thin seed layers prepared by atomic layer deposition on growth of ZnO nanowire array. Nanoscale Res Lett, 2012, 7(1):368 doi: 10.1186/1556-276X-7-368
[6]
Minami T, Miyata T, Ihara K, et al. Effect of ZnO film deposition methods on the photovoltaic properties of ZnO-Cu2O heterojunction devices. Thin Solid Films, 2006, 494(1/2):47
[7]
Polsongkram D, Chamninok P, Pukird S, et al. Effect of synthesis conditions on the growth of ZnO nanorods via hydrothermal method. Physica B, 2008, 403(19/20):3713
[8]
Um H D, Moiz S A, Park K T, et al. Highly selective spectral response with enhanced responsivity of n-ZnO/p-Si radial heterojunction nanowire photodiode. Appl Phys Lett, 2011, 98(3):033102 doi: 10.1063/1.3543845
[9]
Kale V S, Prabhakar R R, Pramana S S, et al. Enhanced electron field emission properties of high aspect ratio silicon nanowire-zinc oxide core-shell arrays. Phys Chem Chem Phys, 2012, 14(13):4614 doi: 10.1039/c2cp40238f
[10]
Kang H, Park J, Choi T, et al. n-ZnO:N/p-Si nanowire photodiode prepared by atomic layer deposition. Appl Phys Lett, 2012, 100(4):041117 doi: 10.1063/1.3679078
[11]
Sun L, He H, Liu C, et al. Controllable growth and optical properties of ZnO nanostructures on Si nanowire arrays. Cryst Engg Comm, 2011, 13(7):2439 doi: 10.1039/c0ce00844c
[12]
Sun K, Jing Y, Park N, et al. Solution synthesis of large-scale, high-sensitivity ZnO/Si hierarchical nanoheterostructure photodetectors. J Am Chem Soc, 2010, 132(44):15465 doi: 10.1021/ja1038424
[13]
Choi J H, Das S N, Moon K J, et al. Fabrication and characterization of p-Si nanowires/ZnO film heterojunction diode. Solid-State Electron, 2010, 54(12):1582 doi: 10.1016/j.sse.2010.07.015
[14]
Zhou H, Fang G, Yuan L, et al. Deep ultraviolet and near infrared photodiode based on n-ZnO/p-silicon nanowire heterojunction fabricated at low temperature. Appl Phys Lett, 2009, 94(1):013503 doi: 10.1063/1.3064161
[15]
Hu J, Chen Z, Sun Y, et al. ZnO-Si side-to-side biaxial nanowire heterostructures with improved luminescence. J Mater Chem, 2009, 19(38):7011 doi: 10.1039/b902201e
[16]
Kim K, Moona T, Lee M, et al. Light-emitting diodes composed of n-ZnO and p-Si nanowires constructed on plastic substrates by dielectrophoresis. Solid State Sci, 2011, 13(9):1735 doi: 10.1016/j.solidstatesciences.2011.06.028
[17]
Hazra P, Jit S. An In-house approach for fabrication of silicon nanowire arrays using electroless metal deposition and etching method. Int J Surf Sci Eng, 2013, 7(3):285 doi: 10.1504/IJSURFSE.2013.056439
[18]
Chen Y, Pu Y, Wang L, et al. Influence of nitrogen annealing on structural and photoluminescent properties of ZnO thin film grown on c-Al2O3 by atmospheric pressure MOCVD. Mat Sci Semicond Proc, 2005, 8(4):491 doi: 10.1016/j.mssp.2004.07.006
[19]
Yakuphanoglu F. The current-voltage characteristics of FSS/n-Si heterojunction diode under dark and illumination. Physica B, 2007, 388(1/2):226
[20]
Seo O, Kim H, Jo J. Anomalous capacitance change in low-temperature grown ZnO thin-film transistors. Eur Phys J Appl Phys, 2010, 52(1):10501 doi: 10.1051/epjap/2010129
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    Received: 28 June 2013 Revised: 14 August 2013 Online: Published: 01 January 2014

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      Purnima Hazra, S. Jit. A p-silicon nanowire/n-ZnO thin film heterojunction diode prepared by thermal evaporation[J]. Journal of Semiconductors, 2014, 35(1): 014001. doi: 10.1088/1674-4926/35/1/014001 P Hazra, S. Jit. A p-silicon nanowire/n-ZnO thin film heterojunction diode prepared by thermal evaporation[J]. J. Semicond., 2014, 35(1): 014001. doi: 10.1088/1674-4926/35/1/014001.Export: BibTex EndNote
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      Purnima Hazra, S. Jit. A p-silicon nanowire/n-ZnO thin film heterojunction diode prepared by thermal evaporation[J]. Journal of Semiconductors, 2014, 35(1): 014001. doi: 10.1088/1674-4926/35/1/014001

      P Hazra, S. Jit. A p-silicon nanowire/n-ZnO thin film heterojunction diode prepared by thermal evaporation[J]. J. Semicond., 2014, 35(1): 014001. doi: 10.1088/1674-4926/35/1/014001.
      Export: BibTex EndNote

      A p-silicon nanowire/n-ZnO thin film heterojunction diode prepared by thermal evaporation

      doi: 10.1088/1674-4926/35/1/014001
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      • Corresponding author: Purnima Hazra, Email: phazra.rs.ece@itbhu.ac.in
      • Received Date: 2013-06-28
      • Revised Date: 2013-08-14
      • Published Date: 2014-01-01

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