SEMICONDUCTOR MATERIALS

Oriented colloidal-crystal thin films of polystyrene spheres via spin coating

S. S. Shinde and S. Park

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 Corresponding author: S. S. Shinde, E-mail: physics.sambhaji2006@gmail.com

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Abstract: We developed a simple and inexpensive synthesis of a large-scale close-packed monolayer of polystyrene sphere arrays, which have a variety of applications. The influence of three step spin speeds, spinning time, solution quantity and relative humidity is studied in order to achieve a large area close-packed monolayer. A relatively high surface coverage and uniform monolayer of PS spheres in the range of 85%—90% are achieved by appropriate control of the preparative parameters. Also the effect of the oxygen plasma etching process on the reduction of PS spheres has been studied. We conclude that it can be useful in industrial applications, because of the fabrication speed, surface coverage, control over PS spheres and cost of the process.

Key words: monolayerPS spheresoxygen plasma



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Fig. 1.  SEM images of PS spheres monolayer on the p-silicon wafer fabricated at different first step spin rates from 100-500 rpm.

Fig. 2.  SEM images of PS spheres monolayers on the p-silicon wafer fabricated at different second step spin rates from 500-2000 rpm.

Fig. 3.  SEM images of PS spheres monolayers on the p-silicon wafer deposited for various third step spin rates from 2000-8000 rpm.

Fig. 4.  SEM images of PS spheres monolayers fabricated at different first step spinning times ranging from 10-40 s.

Fig. 5.  SEM images of PS spheres monolayers fabricated at different second step spinning times ranging from 20-80 s.

Fig. 6.  SEM images of PS spheres monolayers developed at different third step spinning times ranging from 5-20 s.

Fig. 7.  SEM images of PS spheres monolayers fabricated at various concentrations from 3-10 wt %.

Fig. 8.  SEM images of oxygen plasma etched PS spheres at various etching times 0-50 s.

Fig. 9.  The distribution of particles before and after oxygen plasma etching.

Fig. 10.  Relation between PS diameter and oxygen etching time.

Fig. 11.  SEM images etched PS spheres at different DC powers.

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    Received: 02 September 2014 Revised: Online: Published: 01 February 2015

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      S. S. Shinde, S. Park. Oriented colloidal-crystal thin films of polystyrene spheres via spin coating[J]. Journal of Semiconductors, 2015, 36(2): 023001. doi: 10.1088/1674-4926/36/2/023001 S. S. Shinde, S. Park. Oriented colloidal-crystal thin films of polystyrene spheres via spin coating[J]. J. Semicond., 2015, 36(2): 023001. doi: 10.1088/1674-4926/36/2/023001.Export: BibTex EndNote
      Citation:
      S. S. Shinde, S. Park. Oriented colloidal-crystal thin films of polystyrene spheres via spin coating[J]. Journal of Semiconductors, 2015, 36(2): 023001. doi: 10.1088/1674-4926/36/2/023001

      S. S. Shinde, S. Park. Oriented colloidal-crystal thin films of polystyrene spheres via spin coating[J]. J. Semicond., 2015, 36(2): 023001. doi: 10.1088/1674-4926/36/2/023001.
      Export: BibTex EndNote

      Oriented colloidal-crystal thin films of polystyrene spheres via spin coating

      doi: 10.1088/1674-4926/36/2/023001
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      • Corresponding author: E-mail: physics.sambhaji2006@gmail.com
      • Received Date: 2014-09-02
      • Published Date: 2015-01-25

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