SEMICONDUCTOR MATERIALS

Physical vapor transport crystal growth of ZnO

Yang Liu, Jianping Ma, Fuli Liu, Yuan Zang and Yantao Liu

+ Author Affiliations

 Corresponding author: Ma Jianping, Email:majp@xaut.edu.cn

PDF

Abstract: Zinc oxide (ZnO) has a wide band gap, high stability and a high thermal operating range that makes it a suitable material as a semiconductor for fabricating light emitting diodes (LEDs) and laser diodes, photodiodes, power diodes and other semiconductor devices. Recently, a new crystal growth for producing ZnO crystal boules was developed, which was physical vapor transport (PVT), at temperatures exceeding 1500℃ under a certain system pressure. ZnO crystal wafers in sizes up to 50 mm in diameter were produced. The conditions of ZnO crystal growth, growth rate and the quality of ZnO crystal were analyzed. Results from crystal growth and material characterization are presented and discussed. Our research results suggest that the novel crystal growth technique is a viable production technique for producing ZnO crystals and substrates for semiconductor device applications.

Key words: ZnOcrystal boulesphysical vapor transport (PVT)sublimationimpurity analysisgrowth rate



[1]
Look D C. Recent advances in ZnO materials and devices. Mater Sci Eng, 2001, B80:383 https://works.bepress.com/david_look/231/
[2]
Molnar R J, Maki P, Aggarwal R, et al. Gallium nitride thick films grown by hydride vapor phase epitaxy. Mat Res Soc Sympo Proc, 1996, 423:221 doi: 10.1557/PROC-423-221
[3]
Paszkiewicz R, Paszkiewicz B, Korbutowicz R, et al. MOVPE GaN grown on alternative substrates. J Cryst Res Technol, 2001, 36:971 doi: 10.1002/(ISSN)1521-4079
[4]
Sakagami N. Hydrothermal growth and characterization of ZnO single crystals of high purity. J Cryst Growth, 1990, 99:905 doi: 10.1016/S0022-0248(08)80050-4
[5]
Maeda K, Sato M, Niikura I, et al. Growth of 2 inch ZnO bulk single crystals by the hydrothermal method. Semicond Sci Technol, 2005, 20(4):S49 doi: 10.1088/0268-1242/20/4/006
[6]
Ohshima E, Ogino H, Niikura I, et al. Growth of the 2-in-size bulk ZnO single crystals by the hydrothermal method. J Cryst Growth, 2004, 260(1/2):166
[7]
Klimm D, Ganschow S, Schulz S, et al. The growth of ZnO crystals from the melt. J Cryst Growth, 2008, 310(12):3009 doi: 10.1016/j.jcrysgro.2008.02.027
[8]
Grasza K, Mycielski A. Contactless CVT growth of ZnO crystals. Phys Status Solidi, 2005, 2(3):1115 doi: 10.1002/(ISSN)1610-1642
[9]
Cantwell G, Zhang J, Song J J. Vapor transport growth of ZnO substrates and homoepitaxy of ZnO device layers. In:Litton C W, Reynolds D C, Collins T C, ed. Zinc oxide materials for electronic and optoelectronic device applications. John Wiley & Sons Ltd, 2011:171
[10]
Ntep J M, Barbe M, Cohen-Solal G, et al. ZnO growth by chemically assisted sublimation. J Cryst Growth, 1998, 184/185:1206 http://www.sciencedirect.com/science/article/pii/S0022024898802145?via%3Dihub
[11]
Li X, Xu J, Jin M, et al. Growth of ZnO single crystals by an induced nucleation from a high temperature solution of the ZnO-PbF2 system. Cryst Res Technol, 2007, 42(3):221 doi: 10.1002/(ISSN)1521-4079
[12]
Fujii T, Yoshii N, Masuda R, et al. Nucleation and coalescence behavior for epitaxial ZnO layers on ZnO/sapphire templates grown by halide vapor phase epitaxy. J Cryst Growth, 2009, 311(4):1056 doi: 10.1016/j.jcrysgro.2008.12.026
[13]
Rojo J C, Liang S, Chen H, et al. Physical vapor transport crystal growth of ZnO. In:Teherani F H, Litton C W, ed. Zinc oxide material and device. Proc SPIE, 2006, 6122:61220Q1 doi: 10.1088/1674-4926/35/3/033001
[14]
Wang S, Kopec A, Timmerman A G. Growth and characterization of large-diameter, lithium-free ZnO single crystals. In:Teherani F H, Look D C, Rogers D J, ed. Proc SPIE, 2012, 8263:82630E doi: 10.1117/12.914059
[15]
Wang S. Method for production of zinc oxide single crystals. USA Patent, No. 2012/0086001
[16]
Wang S. Method and apparatus for zinc oxide single crystal boule growth. USA Patent, No. 7279040
[17]
Zhao Youwen, Dong Zhiyuan. Growth of ZnO single crystal by chemical vapor transport method. Chinese Journal of Semiconductors, 2006, 27(2):336 http://ir.semi.ac.cn/handle/172111/10026
[18]
Zhang Fan, Zhao Youwen, Dong Zhiyuan, et al. Bulk single crystal growth and properties of In-doped ZnO. Journal of Semiconductors, 2008, 29(8):1540 http://www.jos.ac.cn/bdtxbcn/ch/reader/view_abstract.aspx?file_no=08021002&flag=1
Fig. 1.  A schematic drawing of the PVT growth method of a ZnO crystal.

Fig. 2.  A ZnO polycrystalline of about 50 mm in diameter.

Fig. 3.  The XRD diffraction pattern of ZnO PVT growth under different system pressures. (a) 20 Pa. (b) 480 Pa. (c) 2800 Pa.

Fig. 4.  The Raman spectra of ZnO PVT growth under different system pressures. (a) 20 Pa. (b) 480 Pa. (c) 2800 Pa.

Fig. 5.  The SEM micrographs of ZnO PVT growth under different system pressures. (a) 20 Pa. (b) 480 Pa. (c) 2800 Pa.

Table 1.   List of the key growth parameters and the ranges of values in ZnO PVT growth experiments.

[1]
Look D C. Recent advances in ZnO materials and devices. Mater Sci Eng, 2001, B80:383 https://works.bepress.com/david_look/231/
[2]
Molnar R J, Maki P, Aggarwal R, et al. Gallium nitride thick films grown by hydride vapor phase epitaxy. Mat Res Soc Sympo Proc, 1996, 423:221 doi: 10.1557/PROC-423-221
[3]
Paszkiewicz R, Paszkiewicz B, Korbutowicz R, et al. MOVPE GaN grown on alternative substrates. J Cryst Res Technol, 2001, 36:971 doi: 10.1002/(ISSN)1521-4079
[4]
Sakagami N. Hydrothermal growth and characterization of ZnO single crystals of high purity. J Cryst Growth, 1990, 99:905 doi: 10.1016/S0022-0248(08)80050-4
[5]
Maeda K, Sato M, Niikura I, et al. Growth of 2 inch ZnO bulk single crystals by the hydrothermal method. Semicond Sci Technol, 2005, 20(4):S49 doi: 10.1088/0268-1242/20/4/006
[6]
Ohshima E, Ogino H, Niikura I, et al. Growth of the 2-in-size bulk ZnO single crystals by the hydrothermal method. J Cryst Growth, 2004, 260(1/2):166
[7]
Klimm D, Ganschow S, Schulz S, et al. The growth of ZnO crystals from the melt. J Cryst Growth, 2008, 310(12):3009 doi: 10.1016/j.jcrysgro.2008.02.027
[8]
Grasza K, Mycielski A. Contactless CVT growth of ZnO crystals. Phys Status Solidi, 2005, 2(3):1115 doi: 10.1002/(ISSN)1610-1642
[9]
Cantwell G, Zhang J, Song J J. Vapor transport growth of ZnO substrates and homoepitaxy of ZnO device layers. In:Litton C W, Reynolds D C, Collins T C, ed. Zinc oxide materials for electronic and optoelectronic device applications. John Wiley & Sons Ltd, 2011:171
[10]
Ntep J M, Barbe M, Cohen-Solal G, et al. ZnO growth by chemically assisted sublimation. J Cryst Growth, 1998, 184/185:1206 http://www.sciencedirect.com/science/article/pii/S0022024898802145?via%3Dihub
[11]
Li X, Xu J, Jin M, et al. Growth of ZnO single crystals by an induced nucleation from a high temperature solution of the ZnO-PbF2 system. Cryst Res Technol, 2007, 42(3):221 doi: 10.1002/(ISSN)1521-4079
[12]
Fujii T, Yoshii N, Masuda R, et al. Nucleation and coalescence behavior for epitaxial ZnO layers on ZnO/sapphire templates grown by halide vapor phase epitaxy. J Cryst Growth, 2009, 311(4):1056 doi: 10.1016/j.jcrysgro.2008.12.026
[13]
Rojo J C, Liang S, Chen H, et al. Physical vapor transport crystal growth of ZnO. In:Teherani F H, Litton C W, ed. Zinc oxide material and device. Proc SPIE, 2006, 6122:61220Q1 doi: 10.1088/1674-4926/35/3/033001
[14]
Wang S, Kopec A, Timmerman A G. Growth and characterization of large-diameter, lithium-free ZnO single crystals. In:Teherani F H, Look D C, Rogers D J, ed. Proc SPIE, 2012, 8263:82630E doi: 10.1117/12.914059
[15]
Wang S. Method for production of zinc oxide single crystals. USA Patent, No. 2012/0086001
[16]
Wang S. Method and apparatus for zinc oxide single crystal boule growth. USA Patent, No. 7279040
[17]
Zhao Youwen, Dong Zhiyuan. Growth of ZnO single crystal by chemical vapor transport method. Chinese Journal of Semiconductors, 2006, 27(2):336 http://ir.semi.ac.cn/handle/172111/10026
[18]
Zhang Fan, Zhao Youwen, Dong Zhiyuan, et al. Bulk single crystal growth and properties of In-doped ZnO. Journal of Semiconductors, 2008, 29(8):1540 http://www.jos.ac.cn/bdtxbcn/ch/reader/view_abstract.aspx?file_no=08021002&flag=1
  • Search

    Advanced Search >>

    GET CITATION

    shu

    Export: BibTex EndNote

    Article Metrics

    Article views: 2325 Times PDF downloads: 14 Times Cited by: 0 Times

    History

    Received: 12 August 2013 Revised: 27 September 2013 Online: Published: 01 March 2014

    Catalog

      Email This Article

      User name:
      Email:*请输入正确邮箱
      Code:*验证码错误
      Yang Liu, Jianping Ma, Fuli Liu, Yuan Zang, Yantao Liu. Physical vapor transport crystal growth of ZnO[J]. Journal of Semiconductors, 2014, 35(3): 033001. doi: 10.1088/1674-4926/35/3/033001 Y Liu, J P Ma, F L Liu, Y Zang, Y T Liu. Physical vapor transport crystal growth of ZnO[J]. J. Semicond., 2014, 35(3): 033001. doi: 10.1088/1674-4926/35/3/033001.Export: BibTex EndNote
      Citation:
      Yang Liu, Jianping Ma, Fuli Liu, Yuan Zang, Yantao Liu. Physical vapor transport crystal growth of ZnO[J]. Journal of Semiconductors, 2014, 35(3): 033001. doi: 10.1088/1674-4926/35/3/033001

      Y Liu, J P Ma, F L Liu, Y Zang, Y T Liu. Physical vapor transport crystal growth of ZnO[J]. J. Semicond., 2014, 35(3): 033001. doi: 10.1088/1674-4926/35/3/033001.
      Export: BibTex EndNote

      Physical vapor transport crystal growth of ZnO

      doi: 10.1088/1674-4926/35/3/033001
      Funds:

      Project supported by the Special Scientific Research Plan Project of Shaanxi Provincial Education Department, China (No. 08JK376)

      Project supported by the Special Scientific Research Plan Project of Shaanxi Provincial Education Department, China 08JK376

      More Information
      • Corresponding author: Ma Jianping, Email:majp@xaut.edu.cn
      • Received Date: 2013-08-12
      • Revised Date: 2013-09-27
      • Published Date: 2014-03-01

      Catalog

        /

        DownLoad:  Full-Size Img  PowerPoint
        Return
        Return