Fig. 1.
The schematic diagram of the CF|PANI composite.
DownLoad:
| Citation: |
Kexin Li, Gentian Yue, Furui Tan. A binder-free CF|PANI composite electrode with excellent capacitance for asymmetric supercapacitors[J]. Journal of Semiconductors, 2023, 44(3): 032701. doi: 10.1088/1674-4926/44/3/032701
K X Li, G T Yue, F R Tan. A binder-free CF|PANI composite electrode with excellent capacitance for asymmetric supercapacitors[J]. J. Semicond, 2023, 44(3): 032701. doi: 10.1088/1674-4926/44/3/032701
Export: BibTex EndNote
|
A binder-free CF|PANI composite electrode with excellent capacitance for asymmetric supercapacitors
doi: 10.1088/1674-4926/44/3/032701
More Information-
Abstract
In this work, carbon fiber and polyaniline (CF|PANI) composites are prepared by using an electrochemical polymerization method. The morphology and composition characterization results show that the PANI nanospheres are successfully synthesized and uniformly coated on the CF. When the electrodeposition period is 300 cycles, the as-prepared CF|PANI electrode exhibits good specific capacitance of 231.63 F/g at 1 A/g, high performance of 98.14% retention rate from 0.5 to 20 A/g, and excellent cycle stability with only 0.96% capacity loss after 1000 cycles. This is ascribed to the internal resistance that was significantly reduced without binders, which helps to the CF|PANI electrode maintains high operating potential and pseudo-capacitance performance at high current density. The symmetrical supercapacitor based on two CF|PANI electrodes connecting by acidic PVA-H2SO4 gel electrolyte exhibits an energy density of 6.55 W·h/kg at a power density of 564.37 W/kg. In addition, the asymmetric supercapacitor based on MoS2|MWCNTs and CF|PANI electrodes with neutral PVA-Na2SO4 gel electrolyte shows an energy density of 16.12 W·h/kg at a power density of 525.03 W/kg. These results indicate that the low internal resistance contributes to the high energy density of symmetrical supercapacitors and asymmetric supercapacitors at high current density and high power density, which is significant for its practical application. -
References
[1] Amaral M M, Venâncio R, Peterlevitz A C, et al. Recent advances on quasi-solid-state electrolytes for supercapacitors. J Energ Chem, 2022, 67, 697 doi: 10.1016/j.jechem.2021.11.010[2] Liu T C, Sutarsis S, Zhong X Y, et al. An interfacial wetting water based hydrogel electrolyte for high-voltage flexible quasi solid-state supercapacitors. Energy Storage Mater, 2021, 38, 489 doi: 10.1016/j.ensm.2021.03.028[3] Wang P, Zhang Y, Jiang H, et al. Ammonium vanadium oxide framework with stable NH4+ aqueous storage for flexible quasi-solid-state supercapacitor. Chem Eng J, 2022, 427, 131548 doi: 10.1016/j.cej.2021.131548[4] Gu P, Liu W, Hou Q, et al. Lignocellulose-derived hydrogel/aerogel-based flexible quasi-solid-state supercapacitors with high-performance: a review. J Mater Chem A, 2021, 9, 14233 doi: 10.1039/D1TA02281D[5] Fagiolari L, Sampò M, Lamberti A, et al. Integrated energy conversion and storage devices: Interfacing solar cells, batteries and supercapacitors. Energy Storage Mater, 2022, 51, 400 doi: 10.1016/j.ensm.2022.06.051[6] Cherusseri J, Pandey D, Kumar K S, et al. Flexible supercapacitor electrodes using metal–organic frameworks. Nanoscale, 2020, 12, 17649 doi: 10.1039/D0NR03549A[7] Su S, Lai L, Li R, et al. Annealing-assisted dip-coating synthesis of ultrafine Fe3O4 nanoparticles/graphene on carbon cloth for flexible quasi-solid-state symmetric supercapacitors. ACS Appl Energy Mater, 2020, 3, 9379 doi: 10.1021/acsaem.0c01745[8] Chen Q, Miao X, Liu Y, et al. Polyaniline electropolymerized within template of vertically ordered polyvinyl alcohol as electrodes of flexible supercapacitors with long cycle life. Electrochim Acta, 2021, 390, 138819 doi: 10.1016/j.electacta.2021.138819[9] Lee K S, Jeong H T. Development and optimization of ionic liquid based gel polymer electrolyte for all solid-state supercapacitor. J Energy Storage, 2021, 42, 103001 doi: 10.1016/j.est.2021.103001[10] Du P, Dong Y, Dong Y, et al. Fabrication of uniform MnO2 layer-modified activated carbon cloth for high-performance flexible quasi-solid-state asymmetric supercapacitor. J Mater Sci, 2022, 57, 3497 doi: 10.1007/s10853-021-06728-x[11] Wang W, Xu H, Zhao W, et al. Porphyrin-assisted synthesis of hierarchical flower-like polypyrrole arrays based flexible electrode with high areal capacitance. Chem Eng J, 2022, 428, 131089 doi: 10.1016/j.cej.2021.131089[12] Quan B, Meng Y, Li L, et al. Vertical few-layer graphene/metalized Si-nanocone arrays as 3D electrodes for solid-state supercapacitors with large areal capacitance and superior rate capability. Appl Surf Sci, 2017, 404, 238 doi: 10.1016/j.apsusc.2017.01.312[13] Wang K, Zheng B, Mackinder M, et al. Efficient electrophoretic deposition of MXene/reduced graphene oxide flexible electrodes for all-solid-state supercapacitors. J Energy Storage, 2021, 33, 102070 doi: 10.1016/j.est.2020.102070[14] Zang L, Qiao X, Liu Q, et al. High-performance solid-state supercapacitors with designable patterns based on used newspaper. Cellulose, 2020, 27, 1033 doi: 10.1007/s10570-019-02856-5[15] Wang Y, Chu X, Zhu Z, et al. Dynamically evolving 2D supramolecular polyaniline nanosheets for long-stability flexible supercapacitors. Chem Eng J, 2021, 423, 130203 doi: 10.1016/j.cej.2021.130203[16] Huang Z, Li L, Wang Y, et al. Polyaniline/graphene nanocomposites towards high-performance supercapacitors: A review. Comp Comm, 2018, 8, 83 doi: 10.1016/j.coco.2017.11.005[17] Chu X, Zhao X, Zhou Y, et al. An ultrathin robust polymer membrane for wearable solid-state electrochemical energy storage. Nano Energy, 2020, 76, 105179 doi: 10.1016/j.nanoen.2020.105179[18] Heme H N, Alif M S N, Rahat S M S M, et al. Recent progress in polyaniline composites for high capacity energy storage: A review. J Energy Storage, 2021, 42, 103018 doi: 10.1016/j.est.2021.103018[19] Chang X, El-Kady M F, Huang A, et al. 3D graphene network with covalently grafted aniline tetramer for ultralong-life supercapacitors. Adv Funct Mater, 2021, 31, 2102397 doi: 10.1002/adfm.202102397[20] Wei Y, Zheng M, Luo W, et al. All pseudocapacitive MXene-MnO2 flexible asymmetric supercapacitor. J Energy Storage, 2022, 45, 103715 doi: 10.1016/j.est.2021.103715[21] Zhu Y, Wang D, Yan X, et al. Vertical, dense and uniform V2O5 nanoneedle arrays on carbon foam for boosting electrochemical performance. J Energy Storage, 2021, 37, 102492 doi: 10.1016/j.est.2021.102492[22] Sekhar S C, Nagaraju G, Ramulu B, et al. An eco-friendly hot-water therapy towards ternary layered double hydroxides laminated flexible fabrics for wearable supercapatteries. Nano Energy, 2020, 76, 105016 doi: 10.1016/j.nanoen.2020.105016[23] Hong X, Wang X, Li Y, et al. Potassium citrate-derived carbon nanosheets/carbon nanotubes/polyaniline ternary composite for supercapacitor electrodes. Electrochim Acta, 2022, 403, 139571 doi: 10.1016/j.electacta.2021.139571[24] Wang X, Wang Y, Liu D, et al. Opening MXene ion transport channels by intercalating PANI nanoparticles from the self-assembly approach for high volumetric and areal energy density supercapacitors. ACS Appl Mater Interfaces, 2021, 13, 30633 doi: 10.1021/acsami.1c06934[25] Iqbal M Z, Faisal M M, Ali S R, et al. Co-MOF/polyaniline-based electrode material for high performance supercapattery devices. Electrochim Acta, 2020, 346, 136039 doi: 10.1016/j.electacta.2020.136039[26] Majumder M, K. Thakur A, Bhushan M, et al. Polyaniline integration and interrogation on carbon nano-onions empowered supercapacitors. Electrochim Acta, 2021, 370, 137659 doi: 10.1016/j.electacta.2020.137659[27] Xu M, Guo H, Zhang T, et al. High-performance zeolitic imidazolate frameworks derived three-dimensional Co3S4/polyaniline nanocomposite for supercapacitors. J Energy Storage, 2021, 35, 102303 doi: 10.1016/j.est.2021.102303[28] Chen W, Jiang S, Xiao H, et al. Graphene modified polyaniline-hydrogel based stretchable supercapacitor with high capacitance and excellent stretching stability. ChemSusChem, 2021, 14, 938 doi: 10.1002/cssc.202002641[29] Cheng B, Cheng R, Tan F, et al. Highly efficient quasi-solid-state asymmetric supercapacitors based on MoS2/MWCNT and PANI/MWCNT composite electrodes. Nanoscale Res Lett, 2019, 14, 66 doi: 10.1186/s11671-019-2902-5[30] Hsu C, Hu C, Wu T, et al. How the electrochemical reversibility of a battery-type material affects the charge balance and performances of asymmetric supercapacitors. Electrochim Acta, 2014, 146, 759 doi: 10.1016/j.electacta.2014.09.041[31] Singh R, Tripathi C C. Study of graphene based flexible supercapacitors with different gel electrolytes. Mater Today Proc, 2018, 5, 943 doi: 10.1016/j.matpr.2017.11.169[32] Grote F, Zhao H, Lei Y. Self-supported carbon coated TiN nanotube arrays: innovative carbon coating leads to an improved cycling ability for supercapacitor applications. J Mater Chem A, 2015, 3, 3465 doi: 10.1039/C4TA05905K[33] Guo T, Zhou D, Liu W, et al. Recent advances in all-in-one flexible supercapacitors. Sci China Mater, 2021, 64, 27 doi: 10.1007/s40843-020-1417-8[34] Yan J, Fan Z, Sun W, et al. Advanced asymmetric supercapacitors based on Ni(OH)2/Graphene and porous graphene electrodes with high energy density. Adv Funct Mater, 2012, 22, 2632 doi: 10.1002/adfm.201102839[35] Gao Y, Huang K, Wu X, et al. MoS2 nanosheets assembling three-dimensional nanospheres for enhanced-performance supercapacitor. J Alloys Compd, 2018, 741, 174 doi: 10.1016/j.jallcom.2018.01.110[36] Li H, Liang J, Li H, et al. Activated carbon fibers with manganese dioxide coating for flexible fiber supercapacitors with high capacitive performance. J Energ Chem, 2019, 31, 95 doi: 10.1016/j.jechem.2018.05.008[37] Nam M S, Patil U, Park B, et al. A binder free synthesis of 1D PANI and 2D MoS2 nanostructured hybrid composite electrodes by the electrophoretic deposition (EPD) method for supercapacitor application. RSC Adv, 2016, 6, 101592 doi: 10.1039/C6RA16078F[38] Meng Y, Gu D, Zhang F, et al. A family of highly ordered mesoporous polymer resin and carbon structures from organic-organic self-assembly. Chem Mater, 2006, 18, 4447 doi: 10.1021/cm060921u[39] Ren L, Zhang G, Yan Z, et al. Three-dimensional tubular MoS2/PANI hybrid electrode for high rate performance supercapacitor. ACS Appl Mater Interfaces, 2015, 7, 28294 doi: 10.1021/acsami.5b08474[40] Lu X, Hu Y, Wang L, et al. Macroporous carbon/nitrogen-doped carbon nanotubes/polyaniline nanocomposites and their application in supercapacitors. Electrochim Acta, 2016, 189, 158 doi: 10.1016/j.electacta.2015.12.099[41] Luo Y, Zhang H, Guo D, et al. Porous NiCo2O4-reduced graphene oxide (rGO) composite with superior capacitance retention for supercapacitors. Electrochim Acta, 2014, 132, 332 doi: 10.1016/j.electacta.2014.03.179[42] Chen Y, Xu B, Wen J, et al. Design of novel wearable, stretchable, and waterproof cable-type supercapacitors based on high-performance nickel cobalt sulfide-coated etching-annealed yarn electrodes. Small, 2018, 14, 1704373 doi: 10.1002/smll.201704373[43] Liu T, Zhang F, Song Y, et al. Revitalizing carbon supercapacitor electrodes with hierarchical porous structures. J Mater Chem A, 2017, 5, 17705 doi: 10.1039/C7TA05646J[44] Choudhary N, Li C, Moore J, et al. Asymmetric supercapacitor electrodes and devices. Adv Mater, 2017, 29, 1605336 doi: 10.1002/adma.201605336[45] Wang J, Zhang Y, Ye J, et al. Facile synthesis of three-dimensional NiCo2O4 with different morphology for supercapacitors. RSC Adv, 2016, 6, 70077 doi: 10.1039/C6RA14242G[46] Zhang Z, Wang G, Li Y, et al. A new type of ordered mesoporous carbon/polyaniline composites prepared by a two-step nanocasting method for high performance supercapacitor applications. J Mater Chem A, 2014, 2, 16715 doi: 10.1039/C4TA03351E -
Proportional views
