| Citation: |
Pengfei Qu, Guangdi Zhou, Peng Jin, Xu Han, Zhanguo Wang. Evolution of diamond film growth modes under varied plasma conditions: insights from optical emission spectroscopy[J]. Journal of Semiconductors, 2025, In Press. doi: 10.1088/1674-4926/25110003
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P F Qu, G D Zhou, P Jin, X Han, and Z G Wang, Evolution of diamond film growth modes under varied plasma conditions: insights from optical emission spectroscopy[J]. J. Semicond., 2025, accepted doi: 10.1088/1674-4926/25110003
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Evolution of diamond film growth modes under varied plasma conditions: insights from optical emission spectroscopy
DOI: 10.1088/1674-4926/25110003
CSTR: 10.1088/1674-4926/25110003
More Information-
Abstract
The synthesis of high-quality heteroepitaxial diamond films on iridium composite substrates is a critical step toward advancing diamond for electronic and optical applications. Microwave plasma chemical vapor deposition, combined with in situ optical emission spectroscopy, enables precise control over growth modes through plasma parameter tuning. In this study, we examine how methane concentration, microwave power, and gas pressure influence plasma species and, consequently, the growth modes of heteroepitaxial diamond by optical emission spectroscopy and scanning electron microscope. At low nucleation densities, increased methane concentrations promote the transition from faceted polyhedral to ballas structures, driven by elevated C2 radical concentrations in the plasma. Conversely, at higher nucleation densities, gas pressure, and substrate temperature dominate growth mode determination, leading to diverse morphologies, such as planar, polycrystalline, octahedral, and step-flow growth. These findings elucidate the interplay among plasma species, growth parameters, and growth mode, offering critical insights for optimizing growth conditions and preparing heteroepitaxial diamond films in a specific growth mode.-
Keywords:
- heteroepitaxy,
- diamond films,
- growth modes,
- MPCVD,
- OES
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References
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Proportional views



Pengfei Qu got his B.S. degree from Jilin University, Changchun, China, in 2019, and the Ph.D. degree from Institute of Semiconductors, CAS, Beijing, China, in 2024. He is currently pursuing postdoctoral research at the Institute of Semiconductors, CAS. His research interests mainly focus on materials and devices of heteroepitaxial single-crystal diamond.
Peng Jin got his BS and PhD from Nankai University in 1996 and 2001, respectively. He did postdoctoral research at Institute of Semiconductors, CAS. In 2003, he joined Institute of Semiconductors, CAS as an associate professor. In 2009, he was promoted to be a professor. In 2015, he became a professor of UCAS. The current research focuses on semiconductor diamond materials and devices, low dimensional semiconductor materials and devices, scientific instruments, etc.
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