
SEMICONDUCTOR PHYSICS
Chi Yaqing, Zhong Haiqin, Zhang Xueao, Fang Liang and Chang Shengli
Abstract: Periodic disposed quantum dot arrays are very useful for the large scale integration of single electron devices. Gold quantum dot arrays were self-assembled inside pore channels of ordered amino-functionalized mesoporous silica thin films, employing the neutralization reaction between chloroauric acid and amino groups. The diameters of quantum dots are controlled via changing the aperture of pore channels from 2.3 to 8.3 nm, which are characterized by HRTEM, SEM and FT-IR. UV-vis absorption spectra of gold nanoparticle/mesoporous silica composite thin films exhibit a blue shift and intensity drop of the absorption peak as the aperture of mesopores decreases, which represents the energy level change of quantum dot arrays due to the quantum size effect.
Key words: gold quantum dot array
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Article views: 4080 Times PDF downloads: 2664 Times Cited by: 9 Times
Received: 18 August 2015 Revised: 25 May 2009 Online: Published: 01 December 2009
Citation: |
Chi Yaqing, Zhong Haiqin, Zhang Xueao, Fang Liang, Chang Shengli. Confinement of gold quantum dot arrays inside ordered mesoporous silica thin film[J]. Journal of Semiconductors, 2009, 30(12): 122001. doi: 10.1088/1674-4926/30/12/122001
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Chi Y Q, Zhong H Q, Zhang X A, Fang L, Chang S L. Confinement of gold quantum dot arrays inside ordered mesoporous silica thin film[J]. J. Semicond., 2009, 30(12): 122001. doi: 10.1088/1674-4926/30/12/122001.
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The good potential of the ultrathin barrier (UTB) AlGaN/GaN heterostructure has been demonstrated in the fabrication of high uniformity GaN-on-Si power devices and integration of peripheral controlling circuits[1-4]. To integrate GaN power devices with GaN- or even Si-based ICs on the UTB-AlGaN/GaN platform[5, 6], it is highly desirable to develop a CMOS-compatible process[7], in which a low contact resistivity Au-free ohmic contact is critical to both GaN power and RF devices[8-16].
Regrowth of n-type GaN on source–drain region is an effective way to reduce Rc to 0.05–0.15 Ω·mm[17, 18]. However, the procedure adds complexity and a high maintenance cost. N-doped in the ohmic region by ion implantation is also useful while extremely high annealing temperature is needed[19]. Utilizing the TixAly alloy instead of multilayers as contact metal schemes has been demonstrated as being efficient but the required annealing temperature is also high (880 °C)[14]. A low annealing temperature of less than 650 °C is preferred for the Au-free ohmic contact, in order to mitigate high-temperature annealing-induced degradation of the III-nitride surface and dielectric/III-nitride interface[15, 16]. Previous study has optimized the over-etching condition of a low-pressure chemical vapor deposited SiNx (LPCVD-SiNx) passivation layer on the UTB-AlGaN/GaN heterostructure[16], while the obtained ohmic contact resistivity RC of 1.57 Ω·mm remains too high.
To break the RC limit of the uniform-ohmic-recess process, a patterned AlGaN layer structure was proposed on Ti/Al/Ni/Au ohmic contact to a conventional AlGaN/GaN heterostructure[17, 18]. However, further research is needed to investigate the effect of such patterning processes on the Au-free ohmic contact to ultrathin-barrier heterostructures. In this work, to lower down the Ti/Al/Ti/TiN-based Au-free ohmic contact to the UTB-AlGaN/GaN heterostructure, a grid-patterned ohmic-recess process with good over-etching tolerance was developed. A significantly reduced RC of 0.56 Ω·mm was realized at a relative low annealing temperature of 550 °C. CMOS-compatible GaN MIS-HEMTs was also fabricated on the UTB-AlGaN/GaN on the Si platform.
The schematic cross section of the fabricated CMOS-compatible LPCVD-SiNx/AlGaN/GaN MIS-HEMTs is depicted in Fig. 1(a). The UTB-AlGaN/GaN heterostructure wafer used in this work was grown by metal organic chemical vapor deposition (MOCVD) on a 3-inch Si substrate.
The AlGaN barrier consists of a ~1 nm GaN cap, a ~4 nm Al0.25Ga0.75N layer and a ~1 nm AlN interface enhancement layer. The fresh wafers were first cleaned by standard Radio Corporation of America (RCA) treatment, followed by a ~44 nm LPCVD-SiNx deposited immediately at 780 °C. The high deposition temperature ensures compact film quality and good thermal stability of the SiNx film, and moreover provides sufficient thermal budget for the subsequent process[4]. The LPCVD-SiNx layer in the ohmic region was then etched away by low power SF6/CHF3 hybrid plasmas with 20% over-etching time[16], yielding a squared ohmic contact region of 100 × 100 μm2. The 20% over etching resulted in about 2 nm AlGaN barrier removal. Another photolithography was conducted to form uniformly distributed square patterns with separation equal to the side length in the ohmic contact area, as shown in Fig. 1(a). Chlorine-based plasmas were adopted to etching through the AlGaN barrier to expose the GaN buffer. The sides and adjacent spacing of square holes are both 1.5 μm, as measured by a scanning electron microscope (SEM) shown in Fig. 1(b). The recess depth is determined to be ~5 nm (corresponding to ~1 nm over recess of GaN buffer) by an atomic force microscope (AFM), as shown in Fig. 1(c). Then, device isolation was realized by multi-energy argon ion implantation.
The Ti/Al/Ti/TiN ohmic metal stack was then sputtered to cover the ohmic contact region by another photolithography with a proper wet treatment of the etched surface. The source-drain ohmic contact was then annealed at 550 °C for 90 s in N2 ambient. Subsequently, a TiN/Ti/Al/Ti/TiN metal stack was sputtered over the LPCVD-SiNx layer to form a MIS-gated structure. The fabricated MIS-HEMTs were finally annealed at 280 °C for 4 min in N2 ambient to further improve the thermal stability of the gate. The gate length LG, gate-to-source LGS, and gate-to-drain distance LGS of the MIS-HEMTs are 2.25, 1.25, and 1.75 μm, respectively.
The transmission line method (TLM) was used for the determination of RC and RSH for the Au-free ohmic contact utilizing a pre-ohmic micro-patterned recess process, as shown in Fig. 2(a). The typical RC of the Au-free ohmic contact is determined to be 0.56 Ω·mm, about one-third of our previous reported value (1.57 Ω·mm) without the micro-patterned ohmic recess[16]. The corresponding sheet resistance RSH is extracted to be 385 Ω/sq, indicating that the charge-modulated LPCVD-SiNx layer has recovered the 2DEG effectively. To verify the process window of such a micro-patterned ohmic recess, another ohmic-patterned sample with about a 10-nm over-recess of the GaN channel was also fabricated, only resulting in a slight increase of RC, from 0.56 to 0.58 Ω·mm, while with comparable RSH (399 versus 385 Ω/sq), as shown in Fig. 2(a).
Temperature-dependent four-probe measurement was conducted from –50 to 200 °C, in an N2 protecting environment, to explore the contact mechanism of the fabricated Au-free ohmic contact (Fig. 2(b)). RC is observed to vary slightly over the temperature range, while RSH increases with the temperature. The latter is due to optical phonon scattering induced by degradation of 2-D electron gas (2DEG) mobility at high temperature (T > ~ 200 K)[19-21]. In this case, the mobility follows a power law against temperature, since RSH, which is inversely proportional to the mobility, has a power-law relation with a negative power factor[20-22]. Fig. 2(b) shows the fitting curve of RSH and the extracted power index of +2.58 is consistent with reported values[21]. The corresponding specific contact resistivity ρC shown in Fig. 2(c) decreases from 1.95 × 10–5 to 2.01 × 10–6 Ω·cm2 when the temperature increases from –50 to 200 °C[16]. Both ohmic contact mechanisms of the patterned and un-patterned ohmic contacts can be well fitted by the thermionic field emission (TFE) mechanism shown below [16, 20, 23],
ρC=1qA∗k2B√π(ϕB+En)E00cosh(E00kBT)⋅√coth(E00kBT)×exp(ϕB+EnE0−EnkBT), |
(1) |
where
E0=E00coth(E00kBT), |
(2) |
and
E00=qh4π√NDm∗ε, |
(3) |
where A* = 4πm*kB2/h3 is the effective Richardson constant, m* is the effective mass of the tunneling electrons in (Al)GaN, ε is the dielectric constant of (Al)GaN, ФB is Schottky barrier height between (Al)GaN and the ohmic metals, ND is electron carrier concentration, and En is the energy difference between the conduction-band edge and the Fermi level at the AlGaN/GaN interface.
As for the patterned ohmic contact, the TFE fitting yields a Schottky barrier height ФB of 0.31 eV and a ND of 5.5 × 1018 cm–3, in contrast to the value of 0.50 eV and 1.01 × 1019 cm–3 obtained in the un-patterned sample. The lower ФB is due to partial transition of metal/AlGaN to metal/GaN contact because of over-etching of the AlGaN barrier. However, over-etching also results in 2DEG depletion in the micro-patterned region, giving rise to a reduced ND. Further investigation is ongoing to verify the trade-off between ФB and ND and their effects on ρc. Transfer length LT of the fabricated ohmic contacts have also been plotted in Fig. 2(d) with the temperature. The micro-pattern ohmic recess leads to a remarkable reduction of LT in the measured range. And the shorter current flow distance from the metal (semiconductor) to the semiconductor (metal) can be attributed to the larger lateral contact area to collect current.
To shed light on the effect of pattern size on the contact resistance, a survey of state-of-the-art ohmic contacts that adopts a similar pre-ohmic pattern process is summarized in Table 1. It can be observed that whether the AlGaN barrier in the patterned region is partially or fully recessed, the change of LT follows closely with the pattern separation. For instance, LT decreases from 1.45 to 0.35 μm as the separation is reduced from 1.50 (this work) to 0.50 μm[17]. However, there is little correlation between transfer length value and the over-recess depth, since the LT of ohmic-patterned sample with a ~1 nm and ~10 nm over-recess are the same. Further study is needed to investigate the mechanism behind the correlation between LT and the separation of the micro-pattern. Anyway, the micro-patterned ohmic recess could be an efficient method to reduce RC and LT in Au-free ohmic contacts to the UTB-AlGaN/GaN heterostructure, and the shrinking of LT will also do good to the scaling down of the active chip area of GaN-based electronic devices.
AlGaN/GaN heterostructure | Ohmic metal stack | Annealing temperature (°C) | Recessed-AlGaN barrier thickness in the patterned region (nm) | Side length / Separation of pattern (μm) | LT (μm) | RC (Ω·mm) | RSH (Ω/sq) |
30 nm Al0.25Ga0.75N/GaN[24] | TiSi2/TiN | non-alloy | 5 | 5.00/10.00 | 13.41 | 5.86 | 437 |
24 nm Al0.3Ga0.7N/GaN[17] | Ti/Al/Ni/Au | 850 | 15 | 0.50/0.50 | 0.35 | 0.12 | 341 |
2 nm GaN(cap)/18 nm Al0.26Ga0.74N/GaN[18] | Ti/Al/Ni/Au | 790 | 12 | 1.00/1.00 | 1.10 | 0.52 | 475 |
Ti/Al/Ni/Au | 810 | 12 | 1.00/1.00 | 1.00 | 0.48 | 475 | |
Ti/Al/Ni/Au | 790 | over-recess 30 | 1.00/1.00 | 1.06 | 0.51 | 475 | |
Ti/Al/Ni/Au | 810 | over-recess 30 | 1.00/1.00 | 1.06 | 0.50 | 475 | |
(UTB) 1 nm GaN(cap)/ 3 nm Al0.25Ga0.75N/ 1 nm AlN/GaN[16] | Ti/Al/Ti/TiN | 600 | 5 | / | 4.33 | 1.57 | 363 |
(UTB) 1 nm GaN(cap)/ 4 nm Al0.25Ga0.75N/ 1 nm AlN/GaN (This work) | Ti/Al/Ti/TiN | 550 | over-recess ~1 | 1.50/1.50 | 1.45 | 0.56 | 385 |
over-recess ~10 | 1.50/1.50 | 1.45 | 0.58 | 399 |
The pre-ohmic micro-pattered recess process was then implemented in a fabrication of CMOS-compatible LPCVD-SiNx/AlGaN/GaN MIS-HEMTs, with LPCVD-SiNx serving as the gate dielectric. The MIS-HEMTs’ output characteristics are shown in Fig. 3(a). The on-state resistance (RON), as extracted from the linear region of the output curve, composed of ohmic contact resistance 2RC (22.89%), access region resistance Rs + Rd (23.62%) and gate channel resistance RChannel (53.49%), is substantially low owing to the ohmic pattern process. High ON/OFF current ratios (ION/IOFF) are more than 9 × 1010 while low gate leakage (~10–7 mA/mm) is also obtained in transfer measurements (Fig. 3(b)), thanks to the high insulating behavior of the LPCVD-SiNx gate dielectric. Due to the trapping behavior of deep states located at the LPCVD-SiNx/GaN interface, a clockwise threshold voltage (VTH) hysteresis of 0.23 V is observed at a drain bias of 1 V (Fig. 3(b)). A smaller VTH hysteresis, while a relative lower extrinsic transconductance, can be further realized with proper surface treatments[1]. Moreover, the OFF-state drain and gate current of the MIS-HEMTs with LGD of 1.75 μm, are well suppressed towards VDS of 200 V (Fig. 3(c)). Further work on the implementation of the micro-patterned ohmic recess in enhancement-mode AlGaN/GaN (MIS)HEMTs is ongoing.
A pre-ohmic micro-patterned recess process was developed to facilitate low-thermal-budget Au-free ohmic contact to a UTB-AlGaN/GaN heterostructure. The contact mechanism of ohmic-patterned technology on a UTB AlGaN/GaN heterostructure and the relationship between LT and pattern size were revealed. CMOS-process-compatible SiNx/AlGaN/GaN MIS-HEMTs were fabricated with the proposed Au-free ohmic contact and LPCVD-SiNx gate dielectric.
This work was supported by National Natural Science Foundation of China under Grant 61822407, Grant 62074161, and Grant 11634002; in part by the Key Research Program of Frontier Sciences, Chinese Academy of Sciences (CAS) under Grant QYZDB-SSW-JSC012; in part by the National Key Research and Development Program of China under Grant 2016YFB0400105 and Grant 2017YFB0403000; in part by the Youth Innovation Promotion Association of CAS; in part by the University of Chinese Academy of Sciences; and in part by the Opening Project of Key Laboratory of Microelectronic Devices & Integrated Technology, Institute of Microelectronics, CAS.
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