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Defects and Properties of Antimony-Doped ZnO Single Crystal

Zhang Rui, Zhang Fan, Zhao Youwen, Dong Zhiyuan and Yang Jun

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Abstract: Sb-doped ZnO single crystal has been grown at 950℃ by the chemical vapor transport method.Compared to undoped ZnO,the Sb-doped ZnO single crystal is still n-type with an apparent increase of free electron concentration.X-ray photoelectron spectroscopy (XPS) measurement results suggest a possible occupation of the Zn site of the doped Sb in the ZnO single crystal,resulting in the formation of a donor.Blue emission is observed from the PL spectrum of the Sb doped ZnO single crystal,which is related with a shallow donor defect in ZnO.The results indicate that a high concentration of donor defects forms in ZnO after Sb doping at high temperature,making it difficult to obtain p-type material.

Key words: ZnOsingle crystaldopingdefect

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    Received: 18 August 2015 Revised: 24 April 2008 Online: Published: 01 October 2008

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      Zhang Rui, Zhang Fan, Zhao Youwen, Dong Zhiyuan, Yang Jun. Defects and Properties of Antimony-Doped ZnO Single Crystal[J]. Journal of Semiconductors, 2008, 29(10): 1988-1991. ****Zhang R, Zhang F, Zhao Y W, Dong Z Y, Yang J. Defects and Properties of Antimony-Doped ZnO Single Crystal[J]. J. Semicond., 2008, 29(10): 1988.
      Citation:
      Zhang Rui, Zhang Fan, Zhao Youwen, Dong Zhiyuan, Yang Jun. Defects and Properties of Antimony-Doped ZnO Single Crystal[J]. Journal of Semiconductors, 2008, 29(10): 1988-1991. ****
      Zhang R, Zhang F, Zhao Y W, Dong Z Y, Yang J. Defects and Properties of Antimony-Doped ZnO Single Crystal[J]. J. Semicond., 2008, 29(10): 1988.

      Defects and Properties of Antimony-Doped ZnO Single Crystal

      • Received Date: 2015-08-18
      • Accepted Date: 2008-03-26
      • Revised Date: 2008-04-24
      • Published Date: 2008-11-11

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