J. Semicond. > 2021, Volume 42 > Issue 5 > 050201, doi: 10.1088/1674-4926/42/5/050201

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Intramolecular spatial charge transfer enhances TADF efficiency

Baoyi Ren1, Chuantian Zuo2, Yaguang Sun1, and Liming Ding2,

+ Author Affiliations

 Corresponding author: Yaguang Sun, sunyaguang@syuct.edu.cn; Liming Ding, ding@nanoctr.cn

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[1]
Uoyama H, Goushi K, Shizu K, et al. Highly efficient organic light-emitting diodes from delayed fluorescence. Nature, 2012, 492, 234 doi: 10.1038/nature11687
[2]
Yang Z, Mao Z, Xie Z, et al. Recent advances in organic thermally activated delayed fluorescence materials. Chem Soc Rev, 2017, 46, 915 doi: 10.1039/C6CS00368K
[3]
Tsujimoto H, Ha D G, Markopoulos G, et al. Thermally activated delayed fluorescence and aggregation induced emission with through-space charge transfer. J Am Chem Soc, 2017, 139, 4894 doi: 10.1021/jacs.7b00873
[4]
Tang X, Cui L S, Li H C, et al. Highly efficient luminescence from space-confined charge-transfer emitters. Nat Mater, 2020, 19, 1332 doi: 10.1038/s41563-020-0710-z
[5]
Yang S Y, Tian Q S, Yu Y J, et al. Sky-blue thermally activated delayed fluorescence with intramolecular spatial charge transfer based on a dibenzothiophene sulfone emitter. J Org Chem, 2020, 85, 10628 doi: 10.1021/acs.joc.0c01200
[6]
Yang S Y, Wang Y K, Peng C C, et al. Circularly polarized thermally activated delayed fluorescence emitters in through-space charge transfer on asymmetric spiro skeletons. J Am Chem Soc, 2020, 142, 17756 doi: 10.1021/jacs.0c08980
[7]
Wada Y, Nakagawa H, Matsumoto S, et al. Organic light emitters exhibiting very fast reverse intersystem crossing. Nat Photonics, 2020, 14, 643 doi: 10.1038/s41566-020-0667-0
[8]
Wu C, Liu W, Li K, et al. Face-to-face orientation of quasiplanar donor and acceptor enables highly efficient intramolecular exciplex fluorescence. Angew Chem Int Ed, 2021, 60, 3994 doi: 10.1002/anie.202013051
[9]
Wang X Q, Yang S Y, Tian Q S, et al. Multi-layer π-stacked molecules as efficient thermally activated delayed fluorescence emitters. Angew Chem Int Ed, 2021, 60, 5213 doi: 10.1002/anie.202011384
Fig. 1.  (Color online) (a) Through-bond charge transfer. Reproduced with permission[3], Copyright 2017, American Chemical Society. (b) Through-space charge transfer. Reproduced with permission[9], Copyright 2021, Wiley-VCH. (c) The ISCT-TADF emitters[3, 4, 6–9]. d: D–A distance. Reproduced with permissions[6, 8], Copyright 2020, American Chemical Society and Wiley-VCH.

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Table 1.   ISCT-TADF emitters cited in this article.

EmitterλPL (nm)PLQY (%)kRISC (s−1)kR (s−1)HOMO (eV)LUMO (eV)ΔEST (eV)EL performanceRef.
λEL/CIE (nm)/(x, y)EQEmax (%)
XPT56666.0−−−4.99−3.150.001584/−10.0[3]
DM-B49378.00.18 × 1066.75 × 106−6.38−0.710.170488/(0.20, 0.44)27.4[4]
SFOT51289.01.17 × 105−−5.13−2.910.053508/−23.1[6]
TpAT-tFFO48598.01.20 × 1071.10 × 106−6.47−0.900.019498/(0.20, 0.44)19.2[7]
DPXZ-BO51199.02.10 × 1052.36 × 106−5.08−1.980.030−/(0.26, 0.58)23.9[8]
DM-BD149594.20.29 × 1064.41 × 106−5.36−1.990.050−/(0.21, 0.47)28.0[9]
DM-BD249592.80.31 × 1063.03 × 106−5.30−1.950.040−/(0.20, 0.46)26.6[9]
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[1]
Uoyama H, Goushi K, Shizu K, et al. Highly efficient organic light-emitting diodes from delayed fluorescence. Nature, 2012, 492, 234 doi: 10.1038/nature11687
[2]
Yang Z, Mao Z, Xie Z, et al. Recent advances in organic thermally activated delayed fluorescence materials. Chem Soc Rev, 2017, 46, 915 doi: 10.1039/C6CS00368K
[3]
Tsujimoto H, Ha D G, Markopoulos G, et al. Thermally activated delayed fluorescence and aggregation induced emission with through-space charge transfer. J Am Chem Soc, 2017, 139, 4894 doi: 10.1021/jacs.7b00873
[4]
Tang X, Cui L S, Li H C, et al. Highly efficient luminescence from space-confined charge-transfer emitters. Nat Mater, 2020, 19, 1332 doi: 10.1038/s41563-020-0710-z
[5]
Yang S Y, Tian Q S, Yu Y J, et al. Sky-blue thermally activated delayed fluorescence with intramolecular spatial charge transfer based on a dibenzothiophene sulfone emitter. J Org Chem, 2020, 85, 10628 doi: 10.1021/acs.joc.0c01200
[6]
Yang S Y, Wang Y K, Peng C C, et al. Circularly polarized thermally activated delayed fluorescence emitters in through-space charge transfer on asymmetric spiro skeletons. J Am Chem Soc, 2020, 142, 17756 doi: 10.1021/jacs.0c08980
[7]
Wada Y, Nakagawa H, Matsumoto S, et al. Organic light emitters exhibiting very fast reverse intersystem crossing. Nat Photonics, 2020, 14, 643 doi: 10.1038/s41566-020-0667-0
[8]
Wu C, Liu W, Li K, et al. Face-to-face orientation of quasiplanar donor and acceptor enables highly efficient intramolecular exciplex fluorescence. Angew Chem Int Ed, 2021, 60, 3994 doi: 10.1002/anie.202013051
[9]
Wang X Q, Yang S Y, Tian Q S, et al. Multi-layer π-stacked molecules as efficient thermally activated delayed fluorescence emitters. Angew Chem Int Ed, 2021, 60, 5213 doi: 10.1002/anie.202011384

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    Received: 02 March 2021 Revised: Online: Accepted Manuscript: 03 March 2021Uncorrected proof: 04 March 2021Published: 01 May 2021

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      Article Navigation >  Journal of Semiconductors  > 2021  >  42(5): 050201
      Baoyi Ren, Chuantian Zuo, Yaguang Sun, Liming Ding. Intramolecular spatial charge transfer enhances TADF efficiency[J]. Journal of Semiconductors, 2021, 42(5): 050201. doi: 10.1088/1674-4926/42/5/050201 B Y Ren, C T Zuo, Y G Sun, L M Ding, Intramolecular spatial charge transfer enhances TADF efficiency[J]. J. Semicond., 2021, 42(5): 050201. doi: 10.1088/1674-4926/42/5/050201.Export: BibTex EndNote
      Citation:
      Baoyi Ren, Chuantian Zuo, Yaguang Sun, Liming Ding. Intramolecular spatial charge transfer enhances TADF efficiency[J]. Journal of Semiconductors, 2021, 42(5): 050201. doi: 10.1088/1674-4926/42/5/050201

      B Y Ren, C T Zuo, Y G Sun, L M Ding, Intramolecular spatial charge transfer enhances TADF efficiency[J]. J. Semicond., 2021, 42(5): 050201. doi: 10.1088/1674-4926/42/5/050201.
      Export: BibTex EndNote
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      Intramolecular spatial charge transfer enhances TADF efficiency

      doi: 10.1088/1674-4926/42/5/050201
      • 1.

        College of Science, Shenyang University of Chemical Technology, Shenyang 110142, China

      • 2.

        Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China

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      • Author Bio:

        Baoyi Ren received his BS degree in Applied Chemistry from Northeast Normal University and PhD degree in Chemical Metallurgy from Northeastern University in 2012. He has been working at Shenyang University of Chemical Technology since 2000. He was a visiting scholar (2016–2017) at Lawrence Berkeley National Laboratory. He has been an associate professor since 2014. His research focuses on OLEDs and photovoltaics

        Chuantian Zuo received his PhD degree in 2018 from National Center for Nanoscience and Technology (CAS) under the supervision of Professor Liming Ding. Then he did postdoctoral research in CSIRO, Australia. Currently, he is an assistant professor in Liming Ding Group. His research focuses on innovative materials and devices

        Yaguang Sun received his PhD degree from Northeastern University. Now he is a full professor at Shenyang University of Chemical Technology. His research focuses on the synthesis of MOF/COF-based micro-nano crystals for catalysis

        Liming Ding got his PhD from University of Science and Technology of China (was a joint student at Changchun Institute of Applied Chemistry, CAS). He started his research on OSCs and PLEDs in Olle Inganäs Lab in 1998. Later on, he worked at National Center for Polymer Research, Wright-Patterson Air Force Base and Argonne National Lab (USA). He joined Konarka as a Senior Scientist in 2008. In 2010, he joined National Center for Nanoscience and Technology as a full professor. His research focuses on functional materials and devices. He is RSC Fellow, the nominator for Xplorer Prize, and the Associate Editors for Science Bulletin and Journal of Semiconductors

      • Corresponding author: sunyaguang@syuct.edu.cn; ding@nanoctr.cn
      • Received Date: 2021-03-02
      • Published Date: 2021-05-10

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