J. Semicond. > 2021, Volume 42 > Issue 9 > 090202, doi: 10.1088/1674-4926/42/9/090202
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RESEARCH HIGHLIGHTS

Self-assembled monolayers in perovskite solar cells

Liang Chu1, and Liming Ding2,

+ Author Affiliations

 Corresponding author: Liang Chu, chuliang@njupt.edu.cn; Liming Ding, ding@nanoctr.cn

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[1]
Kojima A, Teshima K, Shirai Y, et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J Am Chem Soc, 2009, 131, 6050 doi: 10.1021/ja809598r
[2]
Best research-cell efficiency chart. NREL Photovoltaic Research, 2020, https://www.nrel.gov/pv/cell-efficiency.html
[3]
Chu L, Ahmad W, Liu W, et al. Lead-free halide double perovskite materials: A new superstar toward green and stable optoelectronic applications. Nano-Micro Lett, 2019, 11, 16 doi: 10.1007/s40820-019-0244-6
[4]
Yang Z, Zhang W, Wu S, et al. Slot-die coating large-area formamidinium-cesium perovskite film for efficient and stable parallel solar module. Sci Adv, 2021, 7, 3749 doi: 10.1126/sciadv.abg3749
[5]
Ulman A. Formation and structure of self-assembled monolayers. Chem Rev, 1996, 96, 1533 doi: 10.1021/cr9502357
[6]
Boyd C C, Shallcross R C, Moot T, et al. Overcoming redox reactions at perovskite-nickel oxide interfaces to boost voltages in perovskite solar cells. Joule, 2020, 4, 1759 doi: 10.1016/j.joule.2020.06.004
[7]
Zhang R, Liu W, Hu R, et al. Enhancing perovskite quality and energy level alignment of TiO2 nanorod arrays-based solar cells via interfacial modification. Sol Energy Mater Sol Cells, 2019, 191, 183 doi: 10.1016/j.solmat.2018.11.006
[8]
Dai Z, Yadavalli S K, Chen M, et al. Interfacial toughening with self-assembled monolayers enhances perovskite solar cell reliability. Science, 2021, 372, 618 doi: 10.1126/science.abf5602
[9]
Lin X, Jumabekov A N, Lal N N, et al. Dipole-field-assisted charge extraction in metal-perovskite-metal back-contact solar cells. Nat Comm, 2017, 8, 613 doi: 10.1038/s41467-017-00588-3
[10]
Topolovsek P, Lamberti F, Gatti T, et al. Functionalization of transparent conductive oxide electrode for TiO2-free perovskite solar cells. J Mater Chem A, 2017, 5, 11882 doi: 10.1039/C7TA02405C
[11]
Aktas E, Phung N, Köbler H, et al. Understanding the perovskite/ self-assembled selective contact interface for ultra-stable and highly efficient p–i–n perovskite solar cells. Energy Environ Sci, 2021, 14, 3976 doi: 10.1039/D0EE03807E
[12]
Canil L, Cramer T, Fraboni B, et al. Tuning halide perovskite energy levels. Energy Environ Sci, 2021, 14, 1429 doi: 10.1039/D0EE02216K
Fig. 1.  (Color online) (a) Schematic illustration of the toughness testing. Inset: idealized I-SAM. (b) Toughness of SnO2/perovskite interface without SAMs and with H-SAM or I-SAM. (c) and (d) DFT calculations. Bonding between PbI2-terminated α-FAPbI3 (001) surface and H(CH2)3H (“H-SAM”) (c) or H(CH2)3I (“I-SAM”) (d). (e) The n–i–p planar PSCs with SAMs. (f) J–V curves from reverse (R) and forward (F) scans of champion PSCs without SAMs and with H-SAM or I-SAM. Reprinted with permission[8], copyright 2021, Science. (g) The effect of a surface dipole on perovskite band diagram. Reprinted with permission[12], copyright 2021, Royal Society of Chemistry.

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[1]
Kojima A, Teshima K, Shirai Y, et al. Organometal halide perovskites as visible-light sensitizers for photovoltaic cells. J Am Chem Soc, 2009, 131, 6050 doi: 10.1021/ja809598r
[2]
Best research-cell efficiency chart. NREL Photovoltaic Research, 2020, https://www.nrel.gov/pv/cell-efficiency.html
[3]
Chu L, Ahmad W, Liu W, et al. Lead-free halide double perovskite materials: A new superstar toward green and stable optoelectronic applications. Nano-Micro Lett, 2019, 11, 16 doi: 10.1007/s40820-019-0244-6
[4]
Yang Z, Zhang W, Wu S, et al. Slot-die coating large-area formamidinium-cesium perovskite film for efficient and stable parallel solar module. Sci Adv, 2021, 7, 3749 doi: 10.1126/sciadv.abg3749
[5]
Ulman A. Formation and structure of self-assembled monolayers. Chem Rev, 1996, 96, 1533 doi: 10.1021/cr9502357
[6]
Boyd C C, Shallcross R C, Moot T, et al. Overcoming redox reactions at perovskite-nickel oxide interfaces to boost voltages in perovskite solar cells. Joule, 2020, 4, 1759 doi: 10.1016/j.joule.2020.06.004
[7]
Zhang R, Liu W, Hu R, et al. Enhancing perovskite quality and energy level alignment of TiO2 nanorod arrays-based solar cells via interfacial modification. Sol Energy Mater Sol Cells, 2019, 191, 183 doi: 10.1016/j.solmat.2018.11.006
[8]
Dai Z, Yadavalli S K, Chen M, et al. Interfacial toughening with self-assembled monolayers enhances perovskite solar cell reliability. Science, 2021, 372, 618 doi: 10.1126/science.abf5602
[9]
Lin X, Jumabekov A N, Lal N N, et al. Dipole-field-assisted charge extraction in metal-perovskite-metal back-contact solar cells. Nat Comm, 2017, 8, 613 doi: 10.1038/s41467-017-00588-3
[10]
Topolovsek P, Lamberti F, Gatti T, et al. Functionalization of transparent conductive oxide electrode for TiO2-free perovskite solar cells. J Mater Chem A, 2017, 5, 11882 doi: 10.1039/C7TA02405C
[11]
Aktas E, Phung N, Köbler H, et al. Understanding the perovskite/ self-assembled selective contact interface for ultra-stable and highly efficient p–i–n perovskite solar cells. Energy Environ Sci, 2021, 14, 3976 doi: 10.1039/D0EE03807E
[12]
Canil L, Cramer T, Fraboni B, et al. Tuning halide perovskite energy levels. Energy Environ Sci, 2021, 14, 1429 doi: 10.1039/D0EE02216K

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    Received: 02 June 2021 Revised: Online: Accepted Manuscript: 02 June 2021Uncorrected proof: 03 June 2021Corrected proof: 04 June 2021Published: 01 September 2021

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      Article Navigation >  Journal of Semiconductors  > 2021  >  42(9): 090202
      Liang Chu, Liming Ding. Self-assembled monolayers in perovskite solar cells[J]. Journal of Semiconductors, 2021, 42(9): 090202. doi: 10.1088/1674-4926/42/9/090202 L Chu, L M Ding, Self-assembled monolayers in perovskite solar cells[J]. J. Semicond., 2021, 42(9): 090202. doi: 10.1088/1674-4926/42/9/090202.Export: BibTex EndNote
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      Liang Chu, Liming Ding. Self-assembled monolayers in perovskite solar cells[J]. Journal of Semiconductors, 2021, 42(9): 090202. doi: 10.1088/1674-4926/42/9/090202

      L Chu, L M Ding, Self-assembled monolayers in perovskite solar cells[J]. J. Semicond., 2021, 42(9): 090202. doi: 10.1088/1674-4926/42/9/090202.
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      Self-assembled monolayers in perovskite solar cells

      doi: 10.1088/1674-4926/42/9/090202
      • 1.

        New Energy Technology Engineering Laboratory of Jiangsu Province, Nanjing University of Posts and Telecommunications, Nanjing 210023, China

      • 2.

        Center for Excellence in Nanoscience (CAS), Key Laboratory of Nanosystem and Hierarchical Fabrication (CAS), National Center for Nanoscience and Technology, Beijing 100190, China

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      • Author Bio:

        Liang Chu received his PhD degree from Huazhong University of Science and Technology in 2014. Then he joined Nanjing University of Posts and Telecommunications as a lecturer, and he was promoted to be an associate professor in 2018. His research includes perovskite solar cells, photodetectors, and memristors

        Liming Ding got his PhD from University of Science and Technology of China (was a joint student at Changchun Institute of Applied Chemistry, CAS). He started his research on OSCs and PLEDs in Olle Inganäs Lab in 1998. Later on, he worked at National Center for Polymer Research, Wright-Patterson Air Force Base and Argonne National Lab (USA). He joined Konarka as a Senior Scientist in 2008. In 2010, he joined National Center for Nanoscience and Technology as a full professor. His research focuses on innovative materials and devices. He is RSC Fellow, the nominator for Xplorer Prize, and the Associate Editors for Science Bulletin and Journal of Semiconductors

      • Corresponding author: chuliang@njupt.edu.cn; ding@nanoctr.cn
      • Received Date: 2021-06-02
      • Published Date: 2021-09-10

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