J. Semicond. > 2024, Volume 45 > Issue 7 > 070401

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Sweat-permeable electronic patches by designing three-dimensional liquid diodes

Kangdi Guan1, 2, Di Chen1, 2, Qilin Hua1, 2, and Guozhen Shen1, 2,

+ Author Affiliations

 Corresponding author: Qilin Hua, huaqilin@bit.edu.cn; Guozhen Shen, gzshen@bit.edu.cn

DOI: 10.1088/1674-4926/24040035

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[1]
Yan Z C, Xiong J, Wang B, et al. Recent advances in breathable electronics. Nano Res, 2023, 16, 4130 doi: 10.1007/s12274-022-5039-2
[2]
Hua Q L, Shen G Z. Low-dimensional nanostructures for monolithic 3D-integrated flexible and stretchable electronics. Chem Soc Rev, 2024, 53, 1316 doi: 10.1039/D3CS00918A
[3]
Chen F, Huang Q Y, Zheng Z J. Permeable conductors for wearable and on-skin electronics. Small Struct, 2022, 3, 2100135 doi: 10.1002/sstr.202100135
[4]
Xi J G, Yang H W, Li X Y, et al. Recent advances in tactile sensory systems: Mechanisms, fabrication, and applications. Nanomaterials, 2024, 14, 465 doi: 10.3390/nano14050465
[5]
Hua Q L, Shen G Z. Full-system-integrated neuro-inspired memristor chips for edge intelligence. Sci Bull, 2023, 68, 3108 doi: 10.1016/j.scib.2023.11.042
[6]
Li Q S, Chen G, Cui Y J, et al. Highly thermal-wet comfortable and conformal silk-based electrodes for on-skin sensors with sweat tolerance. ACS Nano, 2021, 15, 9955 doi: 10.1021/acsnano.1c01431
[7]
Ma Z J, Huang Q Y, Xu Q, et al. Permeable superelastic liquid-metal fibre mat enables biocompatible and monolithic stretchable electronics. Nat Mater, 2021, 20, 859 doi: 10.1038/s41563-020-00902-3
[8]
Jiang Z, Chen N, Yi Z G, et al. A 1.3-micrometre-thick elastic conductor for seamless on-skin and implantable sensors. Nat Electron, 2022, 5, 784 doi: 10.1038/s41928-022-00868-x
[9]
Shi X, Zuo Y, Zhai P, et al. Large-area display textiles integrated with functional systems. Nature, 2021, 591, 240 doi: 10.1038/s41586-021-03295-8
[10]
Hua Q L, Shen G Z. A wearable sweat patch for non-invasive and wireless monitoring inflammatory status. J Semicond, 2023, 44, 100401 doi: 10.1088/1674-4926/44/10/100401
[11]
Yeon H, Lee H, Kim Y, et al. Long-term reliable physical health monitoring by sweat pore-inspired perforated electronic skins. Sci Adv, 2021, 7, eabg8459 doi: 10.1126/sciadv.abg8459
[12]
Wang Y, Lee S, Wang H Y, et al. Robust, self-adhesive, reinforced polymeric nanofilms enabling gas-permeable dry electrodes for long-term application. Proc Natl Acad Sci USA, 2021, 118, e2111904118 doi: 10.1073/pnas.2111904118
[13]
Wei R L, Hua Q L, Shen G Z. Wireless multisite sensing systems for continuous physiological monitoring. Sci China Mater, 2024, 1 doi: 10.1007/s40843-024-2910-x
[14]
Pang H, Hua Q L, Shen G Z. Real-time monitoring of oxygenation in deep brain tissue using a wireless photoelectric probe. Sci China Mater, 2024, 67, 1361 doi: 10.1007/s40843-024-2840-4
[15]
Nayeem M O G, Lee S, Jin H, et al. All-nanofiber-based, ultrasensitive, gas-permeable mechanoacoustic sensors for continuous long-term heart monitoring. Proc Natl Acad Sci USA, 2020, 117, 7063 doi: 10.1073/pnas.1920911117
[16]
Zhang B B, Li J Y, Zhou J K, et al. A three-dimensional liquid diode for soft, integrated permeable electronics. Nature, 2024, 628, 84 doi: 10.1038/s41586-024-07161-1
Fig. 1.  (Color online) A three-dimensional liquid diode for soft, integrated permeable electronics[16]. (a) Schematic of the integrated system-level sweat-permeable electronics, consisting of permeable electrodes, 3D-LD, and flexible circuit board. Blue arrow indicates the pathway of the sweat from the skin to the outlet. The exploded view illustrates the unidirectional sweat transport through the electrode, VLD, and HLD. (b) Cross-sectional representation of the 3D-LD, demonstrating unidirectional sweat transport from the skin–device interface to the outlet. (c) Design of serpentine interconnects to facilitate open channels above sweat pores. Scale bar, 0.5 mm. (d) Permeable electrode maintains stable conformal contact on the fingertip under perspiration conditions. Scale bar, 2 mm. (e) Mechanism of the unidirectional sweat transport in the VLD and photograph of the VLD in the sweat-wicking state. Scale bar, 5 mm. (f) Unidirectional sweat-transport mechanism in the HLD and scanning electron microscopy images of the supporting structure. Scale bar, 300 μm. (g) Comparison of PDMS membrane and 3D-LD in terms of gas and sweat permeability. Scale bars, 0.5 cm. (h) Adhesion strength between patches and skin at different time intervals during exercise. Points, mean; error bars, s.d.; n = 3 independent tests. (i) Water vapor transmission rate (WVTR) of the commercial ECG electrode, PDMS, VLD, and 3D-LD. Bar height, mean; error bars, s.d.; n = 5 independent samples. (j) ECG signals recorded from different electrodes before and after exercise. (k) Exploded-view illustrations of the skin-integrated devices featuring a detachable design, highlighting key layers. (l) Photographs of the permeable textile-integrated weather station. Scale bars, 5 cm ( ⅰ ), 2 cm ( ⅱ ).

[1]
Yan Z C, Xiong J, Wang B, et al. Recent advances in breathable electronics. Nano Res, 2023, 16, 4130 doi: 10.1007/s12274-022-5039-2
[2]
Hua Q L, Shen G Z. Low-dimensional nanostructures for monolithic 3D-integrated flexible and stretchable electronics. Chem Soc Rev, 2024, 53, 1316 doi: 10.1039/D3CS00918A
[3]
Chen F, Huang Q Y, Zheng Z J. Permeable conductors for wearable and on-skin electronics. Small Struct, 2022, 3, 2100135 doi: 10.1002/sstr.202100135
[4]
Xi J G, Yang H W, Li X Y, et al. Recent advances in tactile sensory systems: Mechanisms, fabrication, and applications. Nanomaterials, 2024, 14, 465 doi: 10.3390/nano14050465
[5]
Hua Q L, Shen G Z. Full-system-integrated neuro-inspired memristor chips for edge intelligence. Sci Bull, 2023, 68, 3108 doi: 10.1016/j.scib.2023.11.042
[6]
Li Q S, Chen G, Cui Y J, et al. Highly thermal-wet comfortable and conformal silk-based electrodes for on-skin sensors with sweat tolerance. ACS Nano, 2021, 15, 9955 doi: 10.1021/acsnano.1c01431
[7]
Ma Z J, Huang Q Y, Xu Q, et al. Permeable superelastic liquid-metal fibre mat enables biocompatible and monolithic stretchable electronics. Nat Mater, 2021, 20, 859 doi: 10.1038/s41563-020-00902-3
[8]
Jiang Z, Chen N, Yi Z G, et al. A 1.3-micrometre-thick elastic conductor for seamless on-skin and implantable sensors. Nat Electron, 2022, 5, 784 doi: 10.1038/s41928-022-00868-x
[9]
Shi X, Zuo Y, Zhai P, et al. Large-area display textiles integrated with functional systems. Nature, 2021, 591, 240 doi: 10.1038/s41586-021-03295-8
[10]
Hua Q L, Shen G Z. A wearable sweat patch for non-invasive and wireless monitoring inflammatory status. J Semicond, 2023, 44, 100401 doi: 10.1088/1674-4926/44/10/100401
[11]
Yeon H, Lee H, Kim Y, et al. Long-term reliable physical health monitoring by sweat pore-inspired perforated electronic skins. Sci Adv, 2021, 7, eabg8459 doi: 10.1126/sciadv.abg8459
[12]
Wang Y, Lee S, Wang H Y, et al. Robust, self-adhesive, reinforced polymeric nanofilms enabling gas-permeable dry electrodes for long-term application. Proc Natl Acad Sci USA, 2021, 118, e2111904118 doi: 10.1073/pnas.2111904118
[13]
Wei R L, Hua Q L, Shen G Z. Wireless multisite sensing systems for continuous physiological monitoring. Sci China Mater, 2024, 1 doi: 10.1007/s40843-024-2910-x
[14]
Pang H, Hua Q L, Shen G Z. Real-time monitoring of oxygenation in deep brain tissue using a wireless photoelectric probe. Sci China Mater, 2024, 67, 1361 doi: 10.1007/s40843-024-2840-4
[15]
Nayeem M O G, Lee S, Jin H, et al. All-nanofiber-based, ultrasensitive, gas-permeable mechanoacoustic sensors for continuous long-term heart monitoring. Proc Natl Acad Sci USA, 2020, 117, 7063 doi: 10.1073/pnas.1920911117
[16]
Zhang B B, Li J Y, Zhou J K, et al. A three-dimensional liquid diode for soft, integrated permeable electronics. Nature, 2024, 628, 84 doi: 10.1038/s41586-024-07161-1
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    Received: 04 April 2024 Revised: Online: Accepted Manuscript: 07 May 2024Uncorrected proof: 07 May 2024Published: 15 July 2024

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      Kangdi Guan, Di Chen, Qilin Hua, Guozhen Shen. Sweat-permeable electronic patches by designing three-dimensional liquid diodes[J]. Journal of Semiconductors, 2024, 45(7): 070401. doi: 10.1088/1674-4926/24040035 ****K D Guan, D Chen, Q L Hua, and G Z Shen, Sweat-permeable electronic patches by designing three-dimensional liquid diodes[J]. J. Semicond., 2024, 45(7), 070401 doi: 10.1088/1674-4926/24040035
      Citation:
      Kangdi Guan, Di Chen, Qilin Hua, Guozhen Shen. Sweat-permeable electronic patches by designing three-dimensional liquid diodes[J]. Journal of Semiconductors, 2024, 45(7): 070401. doi: 10.1088/1674-4926/24040035 ****
      K D Guan, D Chen, Q L Hua, and G Z Shen, Sweat-permeable electronic patches by designing three-dimensional liquid diodes[J]. J. Semicond., 2024, 45(7), 070401 doi: 10.1088/1674-4926/24040035

      Sweat-permeable electronic patches by designing three-dimensional liquid diodes

      DOI: 10.1088/1674-4926/24040035
      More Information
      • Kangdi Guan received his master's degree in Electronic and Information Engineering at Anhui Normal University in 2023. Currently, he is pursuing further studies at Beijing Institute of Technology. His research focuses on flexible wearable electrochemical sensors and their applications in areas such as health monitoring
      • Di Chen received her B.S. degree from Anhui Normal University (1999) and a Ph.D. degree from the University of Science and Technology of China (2005). Currently, she is a professor at the Beijing Institute of Technology, China. Her research interests focus on designing nano-structures for sustainable energy applications, including energy storage, solar cells, and photocatalysis
      • Qilin Hua received his Ph.D. degree in Microelectronics at University of Chinese Academy of Sciences (UCAS) in 2016. Then, he worked in Tsinghua University (2016−2018) and Beijing Institute of Nanoenergy and Nanosystems CAS (2018−2022). He is currently an associate professor at Beijing Institute of Technology, China. His research interests focus on flexible/stretchable electronics for neuromorphic sensory systems
      • Guozhen Shen received his Ph.D. degree (2003) in Chemistry from University of Science and technology of China. He then conducted research in several countries, including Korea, Japan, US and China. Currently, he is a professor of School of Integrated Circuits and Electronics and director of Institute of Flexible Electronics, Beijing Institute of Technology. His research focused on flexible electronics and printable electronics and their applications in healthcare monitoring, smart robots and related areas
      • Corresponding author: huaqilin@bit.edu.cngzshen@bit.edu.cn
      • Received Date: 2024-04-04
        Available Online: 2024-05-07

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