Citation: |
Zhiwen Liang, Shangfeng Liu, Ye Yuan, Tongxin Lu, Xiaopeng Li, Zirong Wang, Neng Zhang, Tai Li, Xiangdong Li, Qi Wang, Shengqiang Zhou, Kai Kang, Jincheng Zhang, Yue Hao, Xinqiang Wang. High quality 6-inch single-crystalline AlN template for E-mode HEMT power device[J]. Journal of Semiconductors, 2025, 46(3): 032501. doi: 10.1088/1674-4926/24100041
****
Z W Liang, S F Liu, Y Yuan, T X Lu, X P Li, Z R Wang, N Zhang, T Li, X D Li, Q Wang, S Q Zhou, K Kang, J C Zhang, Y Hao, and X Q Wang, High quality 6-inch single-crystalline AlN template for E-mode HEMT power device[J]. J. Semicond., 2025, 46(3), 032501 doi: 10.1088/1674-4926/24100041
|
High quality 6-inch single-crystalline AlN template for E-mode HEMT power device
DOI: 10.1088/1674-4926/24100041
CSTR: 32376.14.1674-4926.24100041
More Information-
Abstract
In the present work, the high uniform 6-inch single-crystalline AlN template is successfully achieved by high temperature annealing technique, which opens up the path towards industrial application in power device. Moreover, the outstanding crystalline-quality is confirmed by Rutherford backscattering spectrometry (RBS). In accompanied with the results from X-ray diffraction, the RBS results along both [0001] and $ [1\bar{2}13] $ reveal that the in-plane lattice is effectively reordered by high temperature annealing. In addition, the constant Φepi angle between [0001] and $ [1\bar{2}13] $ at different depths of 31.54° confirms the uniform compressive strain inside the AlN region. Benefitting from the excellent crystalline quality of AlN template, we can epitaxially grow the enhanced-mode high electron mobility transistor (HEMT) with a graded AlGaN buffer as thin as only ~300 nm. Such an ultra-thin AlGaN buffer layer results in the wafer-bow as low as 18.1 μm in 6-inch wafer scale. The fabricated HEMT devices with 16 μm-LGD exhibits a threshold voltage (VTH) of 1.1 V and a high OFF-state breakdown voltage (VBD) over 1400 V. Furthermore, after 200 V high-voltage OFF-state stress, the current collapse is only 13.6%. Therefore, the advantages of both 6-inch size and excellent crystallinity announces the superiority of single-crystalline AlN template in low-cost electrical power applications.-
Keywords:
- single-crystalline,
- allium nitride,
- template,
- E-mode HEMT
-
References
[1] Wang J M, Xie N, Xu F J, et al. Group-III nitride heteroepitaxial films approaching bulk-class quality. Nat Mater, 2023, 22, 853 doi: 10.1038/s41563-023-01573-6[2] Kneissl M, Seong T Y, Han J, et al. The emergence and prospects of deep-ultraviolet light-emitting diode technologies. Nat Photonics, 2019, 13, 233 doi: 10.1038/s41566-019-0359-9[3] Takao O, Banal R G, Ken K, et al. 100 mW deep-ultraviolet emission from aluminium-nitride-based quantum wells pumped by an electron beam. Nat Photonics, 2010, 4, 767 doi: 10.1038/nphoton.2010.220[4] Zhao W W, A M Javad, Li Lei, et al. 15-GHz epitaxial AlN FBARs on SiC substrates. IEEE Electron Dev Lett, 2023, 44, 903 doi: 10.1109/LED.2023.3268863[5] Hartmann C, Dittmar A, Wollweber J, et al . Bulk AlN growth by physical vapour transport. Semicond Sci Technol, 2014, 29, 084002 doi: 10.1088/0268-1242/29/8/084002[6] Bickermann M, Epelbaum B M, Kazan M. et al. Growth and characterization of bulk AlN substrates grown by PVT. Phys Stat Sol (a), 2005, 202, 531 doi: 10.1002/pssa.200460416[7] Imura M, Nakano K, Narita G, et al. Epitaxial lateral overgrowth of AlN on trench-patterned AlN layers. J Cryst Growth, 2007, 298, 257 doi: 10.1016/j.jcrysgro.2006.10.043[8] Liu S F, Hoo J , Chen Z Y, et al. Effect of a lateral overgrowth process on the strain evolution of AlN films grown on a nanopatterned sapphire substrate for ultraviolet-C light-emitting diode applications. Phys Stat Sol RRL, 2021, 15, 2100363 doi: 10.1002/pssr.202100363[9] Guo Y M, Fang Y L, Yin J Y, et al. Improved structural quality of AlN grown on sapphire by 3D/2D alternation growth. J Cryst Growth, 2017, 464, 119 doi: 10.1016/j.jcrysgro.2017.01.053[10] He C G, Zhao W, Wu H L, et al. High-quality AlN film grown on sputtered AlN/sapphire via growth-mode modification. Cryst Growth Des, 2018, 18, 6816 doi: 10.1021/acs.cgd.8b01045[11] Miyake H, Lin C H, Tokoro K, et al. Preparation of high-quality AlN on sapphire by high-temperature face-to-face annealing. J Cryst Growth, 2016, 456, 155 doi: 10.1016/j.jcrysgro.2016.08.028[12] Liu S F, Yuan Y, Sh S S, et al. Four-inch high quality crack-free AlN layer grown on a high-temperature annealed AlN template by MOCVD. J Semicond, 2021, 42, 122804 doi: 10.1088/1674-4926/42/12/122804[13] Yoshizawa R, Miyake H, Hiramatsu K. Effect of thermal annealing on AlN films grown on sputtered AlN templates by metalorganic vapor phase epitaxy. Jpn J Appl Phys, 2018, 57, 01AD05 doi: 10.7567/JJAP.57.01AD05[14] Fukuyama H, Miyake H, Nishio G, et al. Impact of high-temperature annealing of AlN layer on sapphire and its thermodynamic principle. Jpn J Appl Phys, 2016, 55, 05FL02 doi: 10.7567/JJAP.55.05FL02[15] Liu S F, Yuan Y, Huang L J, et al. Drive high power UVC-LED wafer into low-cost 4-inch era: effect of strain modulation. Adv Funct Mater, 2022, 32, 2112111 doi: 10.1002/adfm.202112111[16] Lu T X, Fang X L, Zhang S B, et al. High speed surface acoustic wave and laterally excited bulk wave resonator based on single-crystal non-polar AlN film. Appl Phys Lett, 2023, 123, 252105 doi: 10.1063/5.0181087[17] Liang Z W, Yuan Ye, Feng W Y, et al. From GaN crystallinity to device performance: Nucleation mode vs surface energy of single-crystalline AlN template. J Alloys Compd, 2024, 1002, 175363 doi: 10.1016/j.jallcom.2024.175363[18] Wang J B, Li X D, Cheng Z B, et al. Suppressing the leakage of GaN HEMTs on single-crystalline AlN templates by buffer optimization. IEEE Trans Electron Dev, 2024, 71, 6609 doi: 10.1109/TED.2024.3466841[19] Nishikata N, Kushida K, Nishimura T, et al. Evaluation of lattice displacement in Mg-implanted GaN by rutherford backscattering spectroscopy. Nucl Instrum Methods Phys Res Sect B, 2017, 409, 302 doi: 10.1016/j.nimb.2017.03.125[20] Sakuta H, Kawano Y, Yamanaka Y, et al. Diffusion of In atoms in InGaN ultra-thin films during post-growth thermal annealing by high-resolution Rutherford backscattering spectrometry. Phys Stat Sol (c), 2005, 2, 2407 doi: 10.1002/pssc.200461296[21] Wang M, Debernardi A, Berencén Y, et al. Breaking the doping limit in silicon by deep impurities. Phys Rev Applied, 2019, 11, 054039 doi: 10.1103/PhysRevApplied.11.054039[22] Pągowska K D, Kozubal M, Taube A, et al. Comparison of defect structure in Si and Ge ion implanted GaN epilayers by RBS/channeling. Nucl Instrum Methods Phys Res Sect B, 2019, 444, 74 doi: 10.1016/j.nimb.2019.01.053[23] Caçador A, Jóźwik P, Magalhães S, et al. Extracting defect profiles in ion-implanted GaN from ion channeling. Mater Sci Semicond Process, 2023, 166, 107702 doi: 10.1016/j.mssp.2023.107702[24] Uesugi K, Shojiki K, Xiao S Y, et al. Effect of the sputtering deposition conditions on the crystallinity of high-temperature annealed AlN films. Coatings, 2021, 11, 956 doi: 10.3390/coatings11080956[25] Metzger T, Höpler R, Born E, et al. Defect structure of epitaxial GaN films determined by transmission electron microscopy and triple-axis X-ray diffractometry. Philos Mag A, 1998, 77, 1013 doi: 10.1080/01418619808221225[26] Ayers J E. The measurement of threading dislocation densities in semiconductor crystals by X-ray diffraction. J Cryst Growth, 1994, 135, 71 doi: 10.1016/0022-0248(94)90727-7[27] Lo C F, Kang T S, Liu L, et al. Isolation blocking voltage of nitrogen ion-implanted AlGaN/GaN high electron mobility transistor structure. Appl Phys Lett, 2010, 97, 262116 doi: 10.1063/1.3533381 -
Supplements
24100041Supplementary Information.pdf
-
Proportional views