Citation: |
Junjun Xue, Jiyuan Huang, Kehan Li, Ping Liu, Yan Gu, Ting Zhi, Yan Dong, Jin Wang. Boosting photoelectrochemical performance on α-Ga2O3 nanowire arrays by indium cation doping for self-powered ultraviolet detection[J]. Journal of Semiconductors, 2025, In Press. doi: 10.1088/1674-4926/25020024
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J J Xue, J Y Huang, K H Li, P Liu, Y Gu, T Zhi, Y Dong, and J Wang, Boosting photoelectrochemical performance on α-Ga2O3 nanowire arrays by indium cation doping for self-powered ultraviolet detection[J]. J. Semicond., 2025, accepted doi: 10.1088/1674-4926/25020024
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Boosting photoelectrochemical performance on α-Ga2O3 nanowire arrays by indium cation doping for self-powered ultraviolet detection
DOI: 10.1088/1674-4926/25020024
CSTR: 32376.14.1674-4926.25020024
More Information-
Abstract
Low power consumption, high responsivity, and self-powering are key objectives for photoelectrochemical ultraviolet detectors. In this research, In-doped α-Ga₂O₃ nanowire arrays were fabricated on FTO substrates through a hydrothermal approach, with subsequent thermal annealing. These arrays were then used as photoanodes to construct a UV photodetector. In doping reduced the bandgap of α-Ga₂O₃, enhancing its absorption of UV light. Consequently, the In-doped α-Ga₂O₃ nanowire arrays exhibited excellent light detection performance. When irradiated by 255 nm deep ultraviolet light, they obtained a responsivity of 38.85 mA/W. Moreover, the detector's response and recovery times are 13 and 8 ms respectively. The In-doped α-Ga₂O₃ nanowire arrays exhibit a responsivity that is about three-fold higher than the undoped one. Due to its superior responsivity, the In-doped device was used to develop a photoelectric imaging system. This study demonstrates that doping α-Ga₂O₃ nanowires with indium is a potent approach for optimizing their photoelectrochemical performance, which also has significant potential for optoelectronic applications. -
References
[1] Chen W, Wang D H, Wang W Y, et al. Manipulating surface band bending of III-nitride nanowires with ambipolar charge-transfer characteristics: A pathway toward advanced photoswitching logic gates and encrypted optical communication. Adv Mater, 2024, 36(1), 2470008 doi: 10.1002/adma.202470008[2] Wang D H, Liu X, Kang Y, et al. Bidirectional photocurrent in p–n heterojunction nanowires. Nat Electron, 2021, 4, 645 doi: 10.1038/s41928-021-00640-7[3] Li L A, Fang S, Chen W, et al. Facile semiconductor p-n homojunction nanowires with strategic p-type doping engineering combined with surface reconstruction for biosensing applications. Nanomicro Lett, 2024, 16(1), 192[4] Xi Z Y, Liu Z, Fang J P, et al. Etching of Ga2O3: An important process for device manufacturing. J Phys D: Appl Phys, 2024, 57(49), 493002 doi: 10.1088/1361-6463/ad773d[5] Xu H J, Weng Y X, Chen K, et al. Ultra-Low BER encrypted communication based on self-powered bipolar photoresponse ultraviolet photodetector. Adv Opt Mater, 2025, 13(4), 2402238 doi: 10.1002/adom.202402238[6] Xu H J, Deng L P, Cheng Y X, et al. Regulating photocurrent polarity reversal point in α-Ga2O3 nanorod arrays for combinational logic circuit applications. ACS Appl Nano Mater, 2024, 7(2), 2359 doi: 10.1021/acsanm.3c05945[7] Ye J H, Jin S, Cheng Y X, et al. Photocurrent ambipolar behavior in phase junction of a Ga2O3 porous nanostructure for solar-blind light control logic devices. ACS Appl Mater Interfaces, 2024, 16(20), 26512 doi: 10.1021/acsami.4c01837[8] Kang Y, Wang D H, Gao Y Z, et al. Achieving record-high photoelectrochemical photoresponse characteristics by employing Co3O4 nanoclusters as hole charging layer for underwater optical communication. ACS Nano, 2023, 17(4), 3901 doi: 10.1021/acsnano.2c12175[9] Zhang N J, Lin Z G, Wang Z, et al. Under-seawater immersion β-Ga2O3 solar-blind ultraviolet imaging photodetector with high photo-to-dark current ratio and fast response. ACS Nano, 2024, 18(1), 652 doi: 10.1021/acsnano.3c08814[10] Zhang M X, Yu H, Li H, et al. Ultrathin In2O3 nanosheets toward high responsivity and rejection ratio visible -blind UV photodetection. Small, 2023, 19(1), 2205623 doi: 10.1002/smll.202205623[11] Liu Y W, Liu B Y, Wu Y, et al. Modification of graphene photodetector by TiO2 prepared by oxygen plasma. J Mater Sci, 2021, 56(18), 10938 doi: 10.1007/s10853-021-05971-6[12] Yu H, Shao Z T, Wang Y X, et al. One Stone, Three Birds: SnO2 Nanosheet Arrays toward Self-Powered Visible-Blind UV Photodetection with High Responsivity and Rejection Ratio. Adv Opt Mater, 2024, 12(5), 2301460 doi: 10.1002/adom.202301460[13] Zhang B H, Wu H X, Feng C, et al. Self-Powered Solar-Blind Photodetectors Based on α-Ga2O3 Nanorod Arrays. ACS Appl Nano Mater, 2022, 5(8), 11956 doi: 10.1021/acsanm.2c03015[14] Huang L J, Hu Z R, He X W, et al. Self-powered solar-blind ultraviolet photodetector based on α-Ga2O3 nanorod arrays fabricated by the water bath method. Opt Mater Express, 2021, 11(7), 2089 doi: 10.1364/OME.431377[15] Chen K, Wang S L, He C, et al. Photoelectrochemical self-powered solar-blind photodetectors based on Ga2O3 nanorod array/electrolyte solid/liquid heterojunctions with a large separation interface of photogenerated carriers. ACS Appl Nano Mater, 2019, 2(10), 6169 doi: 10.1021/acsanm.9b00992[16] Sun H Z, Ye B J, Ge M, et al. Artificial optoelectronic synapses based on Ga2O3 metal-semiconductor-metal solar-blind ultraviolet photodetectors with asymmetric electrodes for neuromorphic computing. Resp Mater, 2025, e20240038[17] Zhang J H, Jiao S J, Wang D B, et al. Solar-blind ultraviolet photodetection of an α-Ga2O3 nanorod array based on photoelectrochemical self-powered detectors with a simple, newly-designed structure. J Mater Chem C, 2019, 7(23), 6867 doi: 10.1039/C9TC01417A[18] He C R, Guo D Y, Chen K, et al. α-Ga2O3 Nanorod Array-Cu2O Microsphere p-n Junctions for Self-Powered Spectrum-Distinguishable Photodetectors. ACS Appl Nano Mater, 2019, 2(7), 4095 doi: 10.1021/acsanm.9b00527[19] Muazzam U U, Raghavan M, Pratiyush A S, et al. High-responsivity (In0.26Ga0.74)2O3 UV detectors on sapphire realized by microwave irradiation-assisted deposition. J Alloys Compd, 2020, 828, 154337 doi: 10.1016/j.jallcom.2020.154337[20] Wang Z, Zheng W, Hu Q C, et al. Pt/(InGa)2O3/n-Si heterojunction-based solar-blind ultraviolet photovoltaic detectors with an ideal absorption cutoff edge of 280 nm. ACS Appl Mater Interfaces, 2021, 13(37), 44568 doi: 10.1021/acsami.1c13006[21] Fang M Z, Zhao W G, Li F F, et al. Fast response solar-blind photodetector with a quasi-zener tunneling effect based on amorphous in-doped Ga2O3 thin films. Sensors, 2019, 20(1), 129 doi: 10.3390/s20010129[22] Guo J C, Sun G W, Fan M M, et al. Hydrothermal growth of an Al-doped α-Ga2O3 nanorod array and its application in self-powered solar-blind UV photodetection based on a photoelectrochemical cell. Micromachines, 2023, 14(7), 1336 doi: 10.3390/mi14071336[23] Feng Q, Li X, Han G Q, et al. (AlGa)2O3 solar-blind photodetectors on sapphire with wider bandgap and improved responsivity. Opt Mater Express, 2017, 7(4), 1240 doi: 10.1364/OME.7.001240[24] Gao Y Y, Feng Q, Feng Z Q, et al. Epitaxial growth of ε-(AlGa)2O3 films on sapphire substrate by PLD and the fabrication of photodetectors. Opt Mater Express, 2021, 11(2), 219 doi: 10.1364/OME.413500[25] Shen L Y, Pan X H, Zhang T, et al. Improved β-Ga2O3 solar-blind deep-ultraviolet thin-film transistor based on Si-doping. J Electron Mater, 2022, 51(7), 3579 doi: 10.1007/s11664-022-09599-3[26] Hu D Q, Wang Y, Wang Y D, et al. Fabrication and properties of a solar-blind ultraviolet photodetector based on Si-doped β-Ga2O3 film grown on p-Si (111) substrate by MOCVD. Optik, 2021, 245, 167708 doi: 10.1016/j.ijleo.2021.167708[27] Zhang Y N, Zhang M, Hu W B, et al. Performance enhancement of solar-blind UV photodetector by doping silicon in β-Ga2O3 thin films prepared using radio frequency magnetron sputtering. Vacuum, 2024, 227, 113399 doi: 10.1016/j.vacuum.2024.113399[28] Fan M M, Lu Y J, Xu K L, et al. Growth and characterization of Sn-doped β-Ga2O3 thin films by chemical vapor deposition using solid powder precursors toward solar-blind ultraviolet photodetection. Appl Surf Sci, 2020, 509, 144867 doi: 10.1016/j.apsusc.2019.144867[29] Feng Q J, Dong Z J, Liu W, et al. High responsivity solar-blind UV photodetector based on single centimeter-sized Sn-doped β-Ga2O3 microwire. Micro Nanostruct, 2022, 167, 207255 doi: 10.1016/j.micrna.2022.207255[30] Xu K C, Gao Z J, Tong J M, et al. Engineering Charge Separation in α-Ga2O3 Nanorod Arrays for Photoelectrochemical UV Detection. ACS Appl Nano Mater, 2024, 7(14), 16018 doi: 10.1021/acsanm.4c01767[31] Xue J J, Wang S S, Tong J M, et al. Achieving a high-responsivity and fast-response-speed solar-blind photodetector for underwater optical communication via AlGaN/AlN/GaN heterojunction Nanowires. ACS Appl Electron Mater, 2024, 6(6), 4643 doi: 10.1021/acsaelm.4c00636[32] Wang D H, Wu W T, Fang S, et al. Observation of polarity-switchable photoconductivity in III-nitride/MoSx core-shell nanowires. Light Sci Appl, 2022, 11(1), 227 doi: 10.1038/s41377-022-00912-7[33] Fang S, Li L A, Wang W Y, et al. Light-induced bipolar photoresponse with amplified photocurrents in an electrolyte-assisted bipolar p-n junction. Adv Mater, 2023, 35(28), e2300911 doi: 10.1002/adma.202300911[34] Ding S, Chen K, Xiu X Q, et al. β-Ga2O3 nanotube arrays for high-performance self-powered ultraviolet photoelectrochemical photodetectors. Nanotechnology, 2024, 35(17), 175205 doi: 10.1088/1361-6528/ad22a6[35] Xue J J, Xu K C, Tong J M, et al. Solar-blind UV photodetectors based on α-Ga2O3 prepared by a two-step hydrothermal method. Opt Quantum Electron, 2024, 56(7), 1247 doi: 10.1007/s11082-024-07174-0[36] Shao Z T, Qu L H, Cui M Q, et al. Achieving high-performance self-powered visible-blind ultraviolet photodetection using alloy engineering. ACS Appl Mater Interfaces, 2023, 15(37), 43994 doi: 10.1021/acsami.3c08077[37] Ding K, Zhang H, Jiang J L, et al. Balancing carrier dynamics in oxygen-vacancy-tuned Amorphous Ga2O3 thin-film self-powered photoelectrochemical-type solar-blind photodetector arrays for underwater imaging. Adv Sci, 2024, 11(43), e2407822 doi: 10.1002/advs.202407822[38] Liu J H, Ji X Q, Li S, et al. Enhanced performance of self-powered solar-blind deep UV photodetectors based on ZnGa2O4/Ga2O3 heterojunctions. IEEE Sens J, 2024, 24(11), 17661 doi: 10.1109/JSEN.2024.3388471 -
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