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Engineering the photoelectrochemical behaviors of ZnO for efficient solar water splitting 190
Mengmeng Ma, Yanbin Huang, Jun Liu, Kong Liu, Zhijie Wang, Chao Zhao, Shengchun Qu, Zhanguo Wang
2020, 41(9): 091702. doi: 10.1088/1674-4926/41/9/091702

Solar water splitting is a promising strategy for the sustainable production of renewable hydrogen and solving the world’s crisis of energy and environment. The third-generation direct bandgap semiconductor of zinc oxide (ZnO) with properties of environmental friendliness and high efficiency for various photocatalytic reactions, is a suitable material for photoanodes because of its appropriate band structure, fine surface structure, and high electron mobility. However, practical applications of ZnO are usually limited by its high recombination rate of photogenerated electron–hole pairs, lack of surface reaction force, inadequate visible light response, and intrinsic photocorrosion. Given the lack of review on ZnO’s application in photoelectrochemical (PEC) water splitting, this paper reviews ZnO’s research progress in PEC water splitting. It commences with the basic principle of PEC water splitting and the structure and properties of ZnO. Then, we explicitly describe the related strategies to solve the above problems of ZnO as a photoanode, including morphology control, doping modification, construction of heterostructure, and the piezo-photoelectric enhancement of ZnO. This review aims to comprehensively describe recent findings and developments of ZnO in PEC water splitting and to provide a useful reference for the further application and development of ZnO nanomaterials in highly efficient PEC water splitting.

A wide-bandgap copolymer donor with a 5-methyl-4H-dithieno[3,2-e:2',3'-g]isoindole-4,6(5H)-dione unit 182
Anxin Sun, Jingui Xu, Guanhua Zong, Zuo Xiao, Yong Hua, Bin Zhang, Liming Ding
2021, 42(10): 100502. doi: 10.1088/1674-4926/42/10/100502

Optimal design of heterogeneously integrated silicon nitride-lithium niobate modulator 141
Rui Zhao, Haizhong Weng, Qing Wan
doi: 10.1088/1674-4926/25120032

Heterogeneously integrated lithium niobate (LN) electro-optic modulators have great potential for high-speed applications, but challenges remain in optimizing performance, particularly in terms of modulation efficiency, bandwidth, and the trade-offs. This work presents an optimized design for a silicon-nitride (Si3N4)-loaded modulator on a thin-film lithium niobate (TFLN) platform, consisting of 300 nm-thick LN film and 300 nm-thick Si3N4 optical waveguide. By systematically optimizing the dielectric layer thickness, electrode parameters, and achieving velocity and impedance matching, we demonstrate a modulator with a bandwidth exceeding 200 GHz. Our collaborative optimization scheme highlights the critical role of reducing the silicon oxide box layer thickness for velocity matching. We show that multiple structural configurations can achieve bandwidths greater than 120 GHz with Vπ·L< 4 V·cm, providing feasibility in low-loss design and fabrication. These findings offer valuable design guidelines for high-performance electro-optic modulators suitable for data communications.

Frequency dependence on polarization switching measurement in ferroelectric capacitors 139
Zhaomeng Gao, Shuxian Lyu, Hangbing Lyu
2022, 43(1): 014102. doi: 10.1088/1674-4926/43/1/014102

Ferroelectric hysteresis loop measurement under high driving frequency generally faces great challenges. Parasitic factors in testing circuits such as leakage current and RC delay could result in abnormal hysteresis loops with erroneous remnant polarization (Pr) and coercive field (Ec). In this study, positive-up-negative-down (PUND) measurement under a wide frequency range was performed on a 10-nm thick Hf0.5Zr0.5O2 ferroelectric film. Detailed analysis on the leakage current and RC delay was conducted as the polarization switching occurs in the FE capacitor. After considering the time lag caused by RC delay, reasonable calibration of current response over the voltage pulse stimulus was employed in the integral of polarization current over time. In such a method, rational P–V loops measured at high frequencies (>1 MHz) was successfully achieved. This work provides a comprehensive understanding on the effect of parasitic factors on the polarization switching behavior of FE films.

Progress in complementary metal-oxide-semiconductor silicon photonics and optoelectronic integrated circuits 134
Hongda Chen, Zan Zhang, Beiju Huang, Luhong Mao, Zanyun Zhang
2015, 36(12): 121001. doi: 10.1088/1674-4926/36/12/121001

Silicon photonics is an emerging competitive solution for next-generation scalable data communications in different application areas as high-speed data communication is constrained by electrical interconnects. Optical interconnects based on silicon photonics can be used in intra/inter-chip interconnects, board-to-board interconnects, short-reach communications in datacenters, supercomputers and long-haul optical transmissions. In this paper, we present an overview of recent progress in silicon optoelectronic devices and optoelectronic integrated circuits(OEICs) based on a complementary metal-oxide-semiconductor-compatible process, and focus on our research contributions. The silicon optoelectronic devices and OEICs show good characteristics, which are expected to benefit several application domains, including communication, sensing, computing and nonlinear systems.

High-speed electro-absorption modulated laser 129
Zhenyao Li, Chen Lyu, Xuliang Zhou, Mengqi Wang, Haotian Qiu, Yejin Zhang, Hongyan Yu, Jiaoqing Pan
2025, 46(11): 111401. doi: 10.1088/1674-4926/25030015

Currently, the global 5G network, cloud computing, and data center industries are experiencing rapid development. The continuous growth of data center traffic has driven the vigorous progress in high-speed optical transceivers for optical interconnection within data centers. The electro-absorption modulated laser (EML), which is widely used in optical fiber communications, data centers, and high-speed data transmission systems, represents a high-performance photoelectric conversion device. Compared to traditional directly modulated lasers (DMLs), EMLs demonstrate lower frequency chirp and higher modulation bandwidth, enabling support for higher data rates and longer transmission distances. This article introduces the composition, working principles, manufacturing processes, and applications of EMLs. It reviews the progress on advanced indium phosphide (InP)-based EML devices from research institutions worldwide, while summarizing and comparing data transmission rates and key technical approaches across various studies.

Improved efficiency and photo-stability of methylamine-free perovskite solar cells via cadmium doping 128
Yong Chen, Yang Zhao, Qiufeng Ye, Zema Chu, Zhigang Yin, Xingwang Zhang, Jingbi You
2019, 40(12): 122201. doi: 10.1088/1674-4926/40/12/122201

Although perovskite solar cells containing methylamine cation can show high power conversion efficiency, stability is a concern. Here, methylamine-free perovskite material CsxFA1–xPbI3 was synthesized by a one-step method. In addition, we incorporated smaller cadmium ions into mixed perovskite lattice to partially replace Pb ions to address the excessive internal strain in perovskite structure. We have found that the introduction of Cd can improve the crystallinity and the charge carrier lifetime of perovskite films. Consequently, a power conversion efficiency as high as 20.59% was achieved. More importantly, the devices retained 94% of their initial efficiency under 1200 h of continuous illumination.

AC-electronic and dielectric properties of semiconducting phthalocyanine compounds:a comparative study 123
Safa'a M. Hraibat, Rushdi M-L. Kitaneh, Mohammad M. Abu-Samreh, Abdelkarim M. Saleh
2013, 34(11): 112001. doi: 10.1088/1674-4926/34/11/112001

The AC-electronic and dielectric properties of different phthalocyanine films (ZnPc, CuPc, FePc, and H2Pc) were investigated over a wide range of temperature. Both real and imaginary parts of the dielectric constant (ε=ε1-iε2) were found to be influenced by temperature and frequency. Qualitatively the behavior was the same for those compounds; however, the central atom, film thickness, and the electrode type play an important role in the variation of their values.The relaxation time, τ, was strongly frequency-dependent at all temperatures and low frequencies, while a weak dependency is observed at higher frequencies. The relaxation activation energy was derived from the slopes of the fitted lines of ln τ and the reciprocal of the temperature (1/T). The values of the activation energy were accounted for the hopping process at low temperatures, while a thermally activated conduction process was dominant at higher temperatures.The maximum barrier height, Wm, was found to be temperature and frequency dependent for all phthalocyanine compounds. The value Wm depends greatly on the nature of the central atom and electrode material type. The correlated barrier hopping model was found to be the appropriate mechanism to describe the charge carrier's transport in phthalocyanine films.

A review of ToF-based LiDAR 120
Jie Ma, Shenglong Zhuo, Lei Qiu, Yuzhu Gao, Yifan Wu, Ming Zhong, Rui Bai, Miao Sun, Patrick Yin Chiang
2024, 45(10): 101201. doi: 10.1088/1674-4926/24040015

In recent years, propelled by the rapid iterative advancements in digital imaging technology and the semiconductor industry, encompassing microelectronic design, manufacturing, packaging, and testing, time-of-flight (ToF)-based imaging systems for acquiring depth information have garnered considerable attention from both academia and industry. This technology has emerged as a focal point of research within the realm of 3D imaging. Owing to its relatively straightforward principles and exceptional performance, ToF technology finds extensive applications across various domains including human−computer interaction, autonomous driving, industrial inspection, medical and healthcare, augmented reality, smart homes, and 3D reconstruction, among others. Notably, the increasing maturity of ToF-based LiDAR systems is evident in current developments. This paper comprehensively reviews the fundamental principles of ToF technology and LiDAR systems, alongside recent research advancements. It elucidates the innovative aspects and technical challenges encountered in both transmitter (TX) and receiver (RX), providing detailed discussions on corresponding solutions. Furthermore, the paper explores prospective avenues for future research, offering valuable insights for subsequent investigations.

Towards engineering in memristors for emerging memory and neuromorphic computing: A review 120
Andrey S. Sokolov, Haider Abbas, Yawar Abbas, Changhwan Choi
2021, 42(1): 013101. doi: 10.1088/1674-4926/42/1/013101

Resistive random-access memory (RRAM), also known as memristors, having a very simple device structure with two terminals, fulfill almost all of the fundamental requirements of volatile memory, nonvolatile memory, and neuromorphic characteristics. Its memory and neuromorphic behaviors are currently being explored in relation to a range of materials, such as biological materials, perovskites, 2D materials, and transition metal oxides. In this review, we discuss the different electrical behaviors exhibited by RRAM devices based on these materials by briefly explaining their corresponding switching mechanisms. We then discuss emergent memory technologies using memristors, together with its potential neuromorphic applications, by elucidating the different material engineering techniques used during device fabrication to improve the memory and neuromorphic performance of devices, in areas such as ION/IOFF ratio, endurance, spike time-dependent plasticity (STDP), and paired-pulse facilitation (PPF), among others. The emulation of essential biological synaptic functions realized in various switching materials, including inorganic metal oxides and new organic materials, as well as diverse device structures such as single-layer and multilayer hetero-structured devices, and crossbar arrays, is analyzed in detail. Finally, we discuss current challenges and future prospects for the development of inorganic and new materials-based memristors.